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质量水平
方案
98%
旋光性
[α]20/D −10°, neat
折射率
n20/D 1.386 (lit.)
沸点
63 °C (lit.)
密度
0.837 g/mL at 25 °C (lit.)
官能团
ether
SMILES字符串
CC[C@H]1CO1
InChI
1S/C4H8O/c1-2-4-3-5-4/h4H,2-3H2,1H3/t4-/m0/s1
InChI key
RBACIKXCRWGCBB-BYPYZUCNSA-N
应用
(S)-(−)-1,2-Epoxybutane can be used:
- As a starting material to prepare (+)- and (−)-homononactic acids, which are used as intermediates in the total synthesis of a cyclic antibiotic tetranactin.
- To prepare a chiral phosphorus synthon, which is applicable in the synthesis of phytoprostane B1 type I.
- To prepare Eu3+-based precatalysts applicable in the Mukaiyama Aldol reaction in water.
法律信息
经 Shasun Chemicals and Drugs Limited 授权,使用 Jacobsen HKR 技术制造。
警示用语:
Danger
危险分类
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B
储存分类代码
3 - Flammable liquids
WGK
WGK 3
闪点(°F)
10.0 °F - closed cup
闪点(°C)
-12.2 °C - closed cup
个人防护装备
Faceshields, Gloves, Goggles
法规信息
新产品
A flexible synthesis of the phytoprostanes B1 type I and II
The Journal of Organic Chemistry, 70(3), 989-997 (2005)
Synthesis of (+)-and (−)-homononactic acid from (S)-1, 2-epoxybutane. Total synthesis of tetranactin by ′reverse coupe du roi′
Journal of the Chemical Society. Chemical Communications, 996-998 (1986)
Synthesis, spectroscopic characterization, and reactivity of water-tolerant Eu3+-based precatalysts
Inorganic Chemistry, 53(12), 6257-6263 (2014)
Journal of environmental pathology and toxicology, 3(5-6), 171-187 (1980-06-01)
Nitrosopiperidine, sodium nitrite and 1,2 epoxybutane were tested in the Ames agar incorporation assay in an attempt to establish exact criteria for detecting the activity of these weak mutagens. As regards minimum concentrations it was determined that at 500 microgram
Carbohydrate research, 344(15), 1999-2004 (2009-08-26)
A new soluble cyclodextrin derivative 6-O-(2-hydroxybutyl)-beta-cyclodextrin (6-HB-beta-CD) was prepared. Its molecular binding and recognition ability were investigated with the comparison of beta-cyclodextrin (beta-CD), 2-O-(2-hydroxypropyl)-beta-cyclodextrin (2-HP-beta-CD), 6-O-(2-hydroxypropyl)-beta-cyclodextrin (6-HP-beta-CD), and 2-O-(2-hydroxybutyl)-beta-cyclodextrin (2-HB-beta-CD). The relationship between the complex stability constants and the possible
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