mp
>350 °C (lit.)
质量水平
SMILES字符串
CC(C)(C)c1cc2\C=N\[C@H]3CCCC[C@@H]3\N=C\c4cc(cc(c4O[Al](Cl)Oc2c(c1)C(C)(C)C)C(C)(C)C)C(C)(C)C
InChI
1S/C36H54N2O2.Al.ClH/c1-33(2,3)25-17-23(31(39)27(19-25)35(7,8)9)21-37-29-15-13-14-16-30(29)38-22-24-18-26(34(4,5)6)20-28(32(24)40)36(10,11)12;;/h17-22,29-30,39-40H,13-16H2,1-12H3;;1H/q;+3;/p-3/b37-21+,38-22+;;/t29-,30-;;/m0../s1
InChI key
KGVBCKDZFMLRMA-RUIQGICGSA-K
应用
(S,S)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminoaluminum chloride can be used as a chiral catalyst:
- In the preparation of substituted hydroxyalkyl aminooxazole derivatives by reacting isocyanides with aldehydes.
- In the cyanation of α,β-unsaturated imides to yield saturated imides.
法律信息
经 Shasun Chemicals and Drugs Limited 授权销售。
警示用语：
Warning
危险分类
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
Glenn M Sammis et al.
Journal of the American Chemical Society, 126(32), 9928-9929 (2004-08-12)
Cooperative heterobimetallic catalysis was used as a design principle to achieve a highly reactive system for the enantioselective conjugate addition of cyanide to alpha,beta-unsaturated imides. A dual-catalyst pathway involving chiral (salen)Al complex 1b and chiral (pybox)Er complex 4b provides measurable
Highly enantioselective, catalytic conjugate addition of cyanide to alpha, beta-unsaturated imides
Sammis GM and Jacobsen EN
Journal of the American Chemical Society, 125(15), 4442-4443 (2003)
Shi-Xin Wang et al.
Organic letters, 9(18), 3615-3618 (2007-08-10)
In the presence of a catalytic amount of (salen)Al(III)Cl complex (4e), reaction between alpha-isocyanoacetamides (1) and aldehydes (2) afforded the corresponding 5-aminooxazoles (3) in good yields and enantioselectivity.
商品
Salen配体：Jacobsen和Katsuki在1990年分别发表了第一篇关于salen作为锰的配体用于不对称环氧化反应的报道。
The first reports of salen used as ligands with manganese for asymmetric epoxidation reactions.
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