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方案
97%
折射率
n20/D 1.565 (lit.)
沸点
245 °C (lit.)
密度
1.08 g/mL at 25 °C (lit.)
官能团
ketone
SMILES字符串
Cc1ccc(C(C)=O)c(O)c1
InChI
1S/C9H10O2/c1-6-3-4-8(7(2)10)9(11)5-6/h3-5,11H,1-2H3
InChI key
LYKDOWJROLHYOT-UHFFFAOYSA-N
一般描述
2′-Hydroxy-4′-methylacetophenone may be used in the preparation of 4′-methyl-2′-[(p-tolylsulfonyl)oxy]acetophenone.
2′-Hydroxy-4′-methylacetophenone, also known as 1-(2-hydroxy-4-methylphenyl)ethanone can be synthesized by the Fries rearrangement of m-tolyl acetate in the presence of zirconium tetrachloride. The results from the toxicity studies on mite species suggest that 2′-hydroxy-4′-methylacetophenone possesses acaricidal property.
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
10 - Combustible liquids
WGK
WGK 3
闪点(°F)
230.0 °F - closed cup
闪点(°C)
110 °C - closed cup
个人防护装备
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
Min Seok Oh et al.
Journal of agricultural and food chemistry, 60(14), 3606-3611 (2012-03-21)
The acaricidal activities of 2'-hydroxy-4'-methylacetophenone derived from Angelica koreana roots and its derivatives against Dermatophagoides farinae, Dermatophagoides pteronyssinus, and Tyrophagus putrescentiae were examined by vapor phase and contact toxicity bioassays. In the vapor phase toxicity bioassay, 2'-methylacetophenone (1.25 μg/cm(2)) was
4'-Hydroxy-3-methoxyflavones with potent antipicornavirus activity.
De Meyer N, et al.
Journal of Medicinal Chemistry, 34(2), 736-746 (1991)
Zirconium tetrachloride as a mediator for ambient temperature ortho-fries rearrangements.
Harrowven DC and Dainty RF.
Tetrahedron, 37(42), 7659-7660 (1996)
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