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About This Item
线性分子式:
F3COC6H4CHO
CAS号:
分子量:
190.12
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
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质量水平
方案
96%
折射率
n20/D 1.454 (lit.)
沸点
77 °C/20 mmHg (lit.)
密度
1.332 g/mL at 25 °C (lit.)
官能团
aldehyde
fluoro
SMILES字符串
FC(F)(F)Oc1ccccc1C=O
InChI
1S/C8H5F3O2/c9-8(10,11)13-7-4-2-1-3-6(7)5-12/h1-5H
InChI key
CPHXLFKIUVVIOQ-UHFFFAOYSA-N
应用
2-(Trifluoromethoxy)benzaldehyde may be used in the synthesis of tert-butyl N-[4-chloro-2-[α-hydroxy-α-2-(trifluoromethoxy)phenyl]]carbamate.
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
10 - Combustible liquids
WGK
WGK 3
闪点(°F)
153.0 °F - closed cup
闪点(°C)
67.2 °C - closed cup
个人防护装备
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
Frédéric Leroux et al.
The Journal of organic chemistry, 68(12), 4693-4699 (2003-06-07)
Trifluoromethoxy-substituted anilines undergo hydrogen/lithium permutation ("metalation") with optional site selectivity depending on the N-protective group employed. N-tert-Butoxycarbonyl-2- and -4-(trifluoromethoxy)aniline react with tert-butyllithium at the nitrogen-adjacent 6- and 2-position affording, after electrophilic trapping, products 1-6. In contrast, deprotonation of the para
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