528013
二甲基二硫化物
≥99%
别名:
DMDS, 甲基二硫醚
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关于此项目
线性分子式:
CH3SSCH3
化学文摘社编号:
分子量:
94.20
UNSPSC Code:
12352200
NACRES:
NA.22
PubChem Substance ID:
EC Number:
210-871-0
Beilstein/REAXYS Number:
1730824
MDL number:
产品名称
二甲基二硫化物, ≥99%
InChI key
WQOXQRCZOLPYPM-UHFFFAOYSA-N
InChI
1S/C2H6S2/c1-3-4-2/h1-2H3
SMILES string
CSSC
vapor density
3.24 (vs air)
vapor pressure
22 mmHg ( 20 °C)
assay
≥99%
autoignition temp.
>572 °F
expl. lim.
16 %
availability
available only in EU
refractive index
n20/D 1.525 (lit.)
bp
109 °C (lit.)
mp
−85 °C (lit.)
density
1.046 g/mL at 25 °C (lit.)
functional group
disulfide
Quality Level
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Legal Information
Arkema 产品
Application
Dimethyl disulfide can be used:
- For the sulfidation of WS2 nanoparticles during the preparation of WS2/SBA15 mesoporous silica composite.
- In the copper-catalyzed sulfenylation of 2,3-allenoic acids to afford 4-sulfenylated butenolides.
- To synthesize various aryl sulfides by nickel-catalyzed thiolation of aryl iodides.
- Along with triflic anhydride, as a promoter for glycosylation reaction.
- In the copper-catalyzed 1,2-hydroxysulfenylation of alkenes to synthesize 1,2-acetoxysulfides.
- In the synthesis of sulfur containing polycyclic aromatic hydrocarbons such as dibenzoannelated tetrathienoacene.
signalword
Danger
Hazard Classifications
Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2 - Flam. Liq. 2 - Skin Sens. 1 - STOT SE 1 Inhalation - STOT SE 3
target_organs
Central nervous system, Upper respiratory tract
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
59.0 °F - closed cup
flash_point_c
15 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Copper-Catalyzed Sulfenylation, Sulfonylation, and Selenylation of 2, 3-Allenoic Acids with Disulfides or Diselenides.
Xin Y X, et al.
The Journal of Organic Chemistry (2018)
Dibenzoannelated tetrathienoacene: synthesis, characterization, and applications in organic field-effect transistors.
Huang J, et al.
Organic Letters, 14(13), 3300-3303 (2012)
Alkyl-or arylthiolation of aryl iodide via cleavage of the S? S bond of disulfide compound by Nickel Catalyst and Zinc.
Taniguchi N
The Journal of Organic Chemistry, 69(20), 6904-6906 (2004)
Copper-catalyzed 1, 2-hydroxysulfenylation of alkene using disulfide via cleavage of the s? s bond.
Taniguchi N
The Journal of Organic Chemistry, 71(20), 7874-7876 (2006)
A New, Powerful Glycosylation Method: Activation of Thioglycosides with Dimethyl Disulfide? Triflic Anhydride.
Tatai J and Fugedi P
Organic Letters, 9(22), 4647-4650 (2007)
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