所有图片(1)
别名:
4-氰基苄醇
线性分子式:
HOCH2C6H4CN
CAS号:
分子量:
133.15
Beilstein:
2206193
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
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检测方案
95%
mp
39-43 °C (lit.)
SMILES字符串
OCc1ccc(cc1)C#N
InChI
1S/C8H7NO/c9-5-7-1-3-8(6-10)4-2-7/h1-4,10H,6H2
InChI key
XAASLEJRGFPHEV-UHFFFAOYSA-N
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一般描述
4-(Hydroxymethyl)benzonitrile can be synthesized via hydrosilylation reaction in the presence of Fe complex Bu4N[Fe(CO)3(NO)] [catalyst]. It can also be prepared from 4-(aminomethyl) benzyl alcohol.
应用
4-(Hydroxymethyl)benzonitrile [p-(hydroxymethyl)benzonitrile] may be used to synthesize p-((vinyloxy)methyl)benzonitrile (VOMBN).
警示用语：
Warning
危险分类
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
WGK
WGK 3
闪点(°F)
230.0 °F
闪点(°C)
110 °C
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
法规信息
新产品
Bu4N [Fe (CO)3(NO)]-Catalyzed Hydrosilylation of Aldehydes and Ketones.
Dieskau AP, et al.
European Journal of Organic Chemistry, 27, 5291-5296 (2011)
Bergstra?er U, et al.
Science of Synthesis: Houben-Weyl Methods of Molecular Transformations, 219-219 (2014)
Vinyl monomers bearing chromophore moieties and their polymers. VIII. synthesis and fluorescence behavior of a vinyloxy monomer having an electron-accepting chromophore moiety, p-((vinyloxy) methyl) benzonitrile, and its polymers.
Du FS, et al.
Journal of Polymer Science Part A: Polymer Chemistry, 37(2), 179-187 (1999)
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