525693
6-溴-2-吡啶甲醛
97%
别名:
2-溴-6-甲酰基吡啶, 2-溴吡啶-6-甲醛, 2-溴吡啶基-6-甲醛, 2-甲酰基-6-溴吡啶, 6-溴-2-吡啶甲醛, 6-溴-2-甲酰基吡啶, 6-溴吡啶-2-醛
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关于此项目
经验公式（希尔记法）:
C6H4BrNO
化学文摘社编号:
分子量:
186.01
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
产品名称
6-溴-2-吡啶甲醛, 97%
InChI
1S/C6H4BrNO/c7-6-3-1-2-5(4-9)8-6/h1-4H
SMILES string
[H]C(=O)c1cccc(Br)n1
InChI key
QWFHFNGMCPMOCD-UHFFFAOYSA-N
assay
97%
mp
81-85 °C (lit.)
functional group
aldehyde
bromo
storage temp.
2-8°C
Quality Level
Application
6-溴-2-吡啶甲醛可用于合成以下物质：
- 6-([2,2'-二(1,3-二硫环内酯)]-4-基)吡啶醛
- 三条臂之中的某一条上有 3-甲酰基-苯基取代基的 Tpy 核的三(2-吡啶基甲基)胺(Tpy)衍生物
- 顺式和反式 4-(6-溴吡啶-2-基)-3-甲基-3-苯基氧杂环丁烷-2-酮
- 6-(2,4,6-三异丙基苯基)-2-吡啶甲醛
三[(吡啶基)甲基]胺配体的有用合成砌块。
用于研究铑催化的还原性羟醛与二乙烯基酮偶合生成 β-羟基烯酮的底物。
General description
6-溴-2-吡啶甲醛是一种吡啶衍生物。它参与了中位取代的反式 -A2B2-卟啉的合成。
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
ppe
dust mask type N95 (US), Eyeshields, Gloves
法规信息
新产品
此项目有
Francesca A Scaramuzzo et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 19(49), 16809-16813 (2013-11-01)
Reliable determination of the enantiomeric excess of free amino acids can be obtained by measuring the induced circular dichroism of a multicomponent assembly formed by a modified tris(2-pyridylmethyl)amine ligand, a zinc salt, and the amino acid of interest. The systems
Steric and Electronic Effects in the Formation and Carbon Disulfide Reactivity of Dinuclear Nickel Complexes Supported by Bis (iminopyridine) Ligands.
Bheemaraju A, et al.
Organometallics, 32(10), 2952-2962 (2013)
Awatef Ayadi et al.
Beilstein journal of organic chemistry, 11, 1379-1391 (2015-10-02)
The synthesis and full characterization of two tetrathiafulvalene-appended azine ligands, namely 2-([2,2'-bi(1,3-dithiolylidene)]-4-yl)-6-((2,4-dinitrophenyl)hydrazono)methyl)pyridine (L1) and 5-([2,2'-bi(1,3-dithiolylidene)]-4-yl)-2-((2,4-dinitrophenyl)hydrazono)methyl)pyridine (L2) are described. The crystal structure of ligand L1 indicates that the ligand is completely planar with the presence of a strong intramolecular N3-H3···O1 hydrogen
Magdalena M Makowska-Grzyska et al.
Inorganic chemistry, 42(23), 7472-7488 (2003-11-11)
Divalent manganese, cobalt, nickel, and zinc complexes of 6-Ph(2)TPA (N,N-bis((6-phenyl-2-pyridyl)methyl)-N-((2-pyridyl)methyl)amine; [(6-Ph(2)TPA)Mn(CH(3)OH)(3)](ClO(4))(2) (1), [(6-Ph(2)TPA)Co(CH(3)CN)](ClO(4))(2) (2), [(6-Ph(2)TPA)Ni(CH(3)CN)(CH(3)OH)](ClO(4))(2) (3), [(6-Ph(2)TPA)Zn(CH(3)CN)](ClO(4))(2) (4)) and 6-(Me(2)Ph)(2)TPA (N,N-bis((6-(3,5-dimethyl)phenyl-2-pyridyl)methyl)-N-((2-pyridyl)methyl)amine; [(6-(Me(2)Ph)(2)TPA)Ni(CH(3)CN)(2)](ClO(4))(2) (5) and [(6-(Me(2)Ph)(2)TPA)Zn(CH(3)CN)](ClO(4))(2) (6)) have been prepared and characterized. X-ray crystallographic characterization of 1A.CH(3)()OH and 1B.2CH(3)()OH (differing solvates
NHC-Promoted asymmetric β-lactone formation from arylalkylketenes and electron-deficient benzaldehydes or pyridinecarboxaldehydes.
Douglas J, et al.
The Journal of Organic Chemistry, 78(8), 3925-3938 (2013)
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