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质量水平
检测方案
≥99.0%
折射率
n20/D 1.415
bp
65-66 °C (lit.)
密度
0.707 g/mL at 20 °C (lit.)
SMILES字符串
C\C=C/CC=C
InChI
1S/C6H10/c1-3-5-6-4-2/h3-4,6H,1,5H2,2H3/b6-4-
InChI key
PRBHEGAFLDMLAL-XQRVVYSFSA-N
一般描述
cis-1,4-Hexadiene can be synthesized from the cobalt-catalyzed reaction between butadiene and ethylene. The reaction of this hydrocarbon with Fe(CO)5 affords the trans-1,3-hexadiene-iron tricarbonyl complex (I), plus a small amount of the trans,trans-2,4-hexadiene complex(II). Mechanism of the conversion of cis-1,4-hexadiene to trans-2-methyl-1,3-pentadiene, via rearrangement in the presence of a nickel catalyst has been investigated.
警示用语：
Danger
危险声明
预防措施声明
危险分类
Acute Tox. 3 Oral - Asp. Tox. 1 - Flam. Liq. 2
WGK
WGK 3
闪点(°F)
closed cup
闪点(°C)
closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
Reaction of cis-1, 4-Hexadiene with Iron Pentacarbonyl.
Kuji J and Iwamoto M.
Bulletin of the Chemical Society of Japan, 41(6), 1483-1484 (1968)
Nickel-promoted methylvinylcyclopropane rearrangements. Mechanistic relevance to the cis-1, 4-hexadiene to 2-methyl-1, 3-pentadiene isomerization.
Pinke PA, et al.
Journal of the American Chemical Society, 96(13), 4229-4234 (1974)
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