所有图片(3)
别名:
三氯化铑水合物
线性分子式:
RhCl3 · xH2O
CAS号:
分子量:
209.26 (anhydrous basis)
EC 号:
MDL编号:
UNSPSC代码:
12352300
PubChem化学物质编号:
NACRES:
NA.22
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质量水平
检测方案
≥99.9% trace metals basis
形式
crystalline
组成
Rh, 38-43.5%
反应适用性
core: rhodium
reagent type: catalyst
mp
100 °C (dec.) (lit.)
SMILES字符串
O.Cl[Rh](Cl)Cl
InChI
1S/3ClH.H2O.Rh/h3*1H;1H2;/q;;;;+3/p-3
InChI key
HSSMNYDDDSNUKH-UHFFFAOYSA-K
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应用
氯化铑（III）水合物 (RhCl3. xH2O) 可用作制备以下物质的金属前体：
- 用于费托−(FT) 合成的二氧化硅负载铑-钴 (Rh-Co) 催化剂（双金属催化剂）
- 用于酮的不对称还原的铑 (III) 催化剂，N-2-(2,3,4,5 四甲基l环戊二烯基)苄基-(l)-去甲基麻黄碱氯化铑 (III)
- 用于1-辛烯的加氢甲酰化的Rh@CTF（共价三嗪骨架）催化剂
警示用语：
Danger
危险分类
Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Met. Corr. 1 - Muta. 2
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
A new class of Rh (III) catalyst containing an aminoalcohol tethered to a tetramethylcyclopentadienyl group for asymmetric transfer hydrogenation of ketones
Cross DJ, et al.
Tetrahedron Letters, 45(4), 843-846 (2004)
Silica-supported rhodium-cobalt catalysts for Fischer-Tropsch synthesis
Yan Z, et al.
Catalysis Today, 160(1), 39-43 (2011)
N-containing covalent organic frameworks as supports for rhodium as transition-metal catalysts in hydroformylation reactions
Pilaski M, et al.
Microporous and Mesoporous Materials : The Official Journal of the International Zeolite Association, 227(4), 219-227 (2016)
Ligand-induced fate of embryonic species in the shape-controlled synthesis of rhodium nanoparticles.
Adam J Biacchi et al.
ACS nano, 9(2), 1707-1720 (2015-01-30)
The shapes of noble metal nanoparticles directly impact their properties and applications, including in catalysis and plasmonics, and it is therefore important to understand how multiple distinct morphologies can be controllably synthesized. Solution routes offer powerful capabilities for shape-controlled nanoparticle
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