所有图片(1)
About This Item
线性分子式:
PtCl4
CAS号:
分子量:
336.89
EC 号:
MDL编号:
UNSPSC代码:
12352302
PubChem化学物质编号:
NACRES:
NA.23
方案:
≥99.9% trace metals basis
表单:
powder
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质量水平
方案
≥99.9% trace metals basis
表单
powder
组成
Pt, 55-58%
反应适用性
reagent type: catalyst
core: platinum
杂质
≤1000.0 ppm Trace Metal Analysis
mp
370 °C (dec.) (lit.)
密度
4.303 g/mL at 25 °C (lit.)
SMILES字符串
Cl[Pt](Cl)(Cl)Cl
InChI
1S/4ClH.Pt/h4*1H;/q;;;;+4/p-4
InChI key
FBEIPJNQGITEBL-UHFFFAOYSA-J
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一般描述
氯化铂（IV）是一种弱刘易斯酸，用于表面修饰、纳米材料合成和催化。
应用
氯化铂（IV）可用于结晶和无定形二氧化钛粉末的表面修饰，以改善其光催化效率。由于氯化铂（IV）表面络合物在可见光下激发而进入二氧化钛导电带的电子将氧还原成超氧化物。由此形成的超氧化物导致了光降解反应。
铂纳米颗粒可以通过氯化铂（IV）与藻青菌反应以环保的方法来合成。
它还可用作立体和区域选择性糖苷化反应的双功能催化剂。由于其配体结合能力，氯化铂（IV）对糖基受体羟基有亲和力，并形成具有β构型的糖苷化产物。它还可以增强羟基之间的亲核性差异，从而实现区域选择性糖苷化。
铂纳米颗粒可以通过氯化铂（IV）与藻青菌反应以环保的方法来合成。
它还可用作立体和区域选择性糖苷化反应的双功能催化剂。由于其配体结合能力，氯化铂（IV）对糖基受体羟基有亲和力，并形成具有β构型的糖苷化产物。它还可以增强羟基之间的亲核性差异，从而实现区域选择性糖苷化。
警示用语：
Danger
危险分类
Acute Tox. 3 Oral - Eye Dam. 1 - Resp. Sens. 1 - Skin Corr. 1B - Skin Sens. 1
储存分类代码
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGK
WGK 2
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Maggy F Lengke et al.
Langmuir : the ACS journal of surfaces and colloids, 22(17), 7318-7323 (2006-08-09)
Interaction of cyanobacteria (Plectonema boryanum UTEX 485) with aqueous platinum(IV)-chloride (PtCl(4) degrees ) has been investigated at 25-100 degrees C for up to 28 days, and 180 degrees C for 1 day. The addition of PtCl(4) degrees to the cyanobacteria
W Macyk et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 7(9), 1862-1867 (2001-06-19)
Anatase, rutile, and amorphous titania powders were surface-modified by grinding with PtCl4 and H2[PtCl6]. Only the anatase modification afforded hybrid photocatalysts capable of degradation of 4-chlorophenol (4-CP) with visible light, with sufficient stability towards decomplexation. Grinding with K2[PtCl4] produced materials
N Kanematsu et al.
Gifu Shika Gakkai zasshi = The Journal of Gifu Dental Society, 17(2), 575-581 (1990-12-01)
The induction of mutation by cadmium chloride (CdCl2), platinum tetrachloride (PtCl4), and rhodium trichloride (RhCl3.3H2O) was measured utilizing the hypoxanthine-guanine phosphoribosyl transferase (HGPRT) locus in V-79 cells. Cadmium chloride at a concentration of 0.05 microM induced ford mutation in V-79
B A Teicher et al.
Anticancer research, 13(5A), 1549-1556 (1993-09-01)
Since several anticancer drugs are known to become more cytotoxic to cells in an acidic milieu, we have attempted to utilize the carbonic anhydrase inhibitor, Acetazolamide, to acidify the blood and tumor of C3H mice bearing the FSaIIC fibrosarcoma in
A M Reichlmayr-Lais et al.
Journal of trace elements and electrolytes in health and disease, 6(3), 183-187 (1992-09-01)
In experiments with rats dose-response relationships of alimentary PtCl2 and PtCl4 were investigated. 2 x 81 animals weighing 35 g were randomly distributed among 9 treatment groups which were fed ad libitum with a synthetic diet containing various amounts of
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