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Merck
CN

517763

Sigma-Aldrich

2,2′-联吡啶-5,5′-二羧酸

97%

别名:

6,6'-双烟酸

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About This Item

经验公式(希尔记法):
C12H8N2O4
CAS号:
分子量:
244.20
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

方案

97%

mp

>360 °C (lit.)

官能团

carboxylic acid

SMILES字符串

OC(=O)c1ccc(nc1)-c2ccc(cn2)C(O)=O

InChI

1S/C12H8N2O4/c15-11(16)7-1-3-9(13-5-7)10-4-2-8(6-14-10)12(17)18/h1-6H,(H,15,16)(H,17,18)

InChI key

KVQMUHHSWICEIH-UHFFFAOYSA-N

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一般描述

2,2′-Bipyridine-5,5′-dicarboxylic acid also known as 6,6′-Binicotinic acid, is a versatile polypyridyl ligand commonly used in the synthesis of metal–organic frameworks.

应用


  • 含有吡啶和联吡啶羧酸酯有机连接基团和开放Zn2+位点的Zn-MOF:研究讨论了利用2,2′-联吡啶-5,5′-二羧酸作为连接基团的锌基金属有机框架(MOF)的合成和表征,显示了在气体储存和分离中的潜在应用(J Kim et al., 2015)。

  • 含镍(ii) 2,2′-联吡啶配合物的金属有机框架中的乙烯低聚化:报道了使用镍基MOF中2,2′-联吡啶-5,5′-二羧酸催化乙烯低聚化,突出了MOF在催化中的多功能性(MI Gonzalez et al., 2017)。

  • 两种含有2,2′-联吡啶-5,5′-二羧酸的3D金属有机框架:合成、结构和磁性:讨论了用2,2′-联吡啶-5,5′-二羧酸构建的两种3D MOF的合成和磁性,展示了在先进材料中的应用潜力(M Fang et al., 2014)。

象形图

Exclamation mark

警示用语:

Warning

危险声明

危险分类

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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访问文档库

Ruthenium (II) complexes of 2, 2?-bipyridine-5, 5?-dicarboxylic acid: Synthesis, structure, DNA binding, cytotoxicity and antioxidant activity
amatchi TS, et al.
Inorganica chimica acta, 404, 58-67 (2013)
Shaoyang Lin et al.
ChemSusChem, 10(3), 514-522 (2016-12-16)
Water oxidation, a key component in artificial photosynthesis, requires high overpotentials and exhibits slow reaction kinetics that necessitates the use of stable and efficient heterogeneous water-oxidation catalysts (WOCs). Here, we report the synthesis of UiO-67 metal-organic framework (MOF) thin films
Synthesis, structure and luminescence property of Eu (III) metal--organic framework based on 2, 2?-bipyridine-5, 5?-dicarboxylic acid
Liu H, et al.
Inorganic Chemistry Communications, 46, 39-42 (2014)
Woo Hyeong Sim et al.
Advanced science (Weinheim, Baden-Wurttemberg, Germany), 8(1), 2002144-2002144 (2021-01-14)
Lithium (Li) metal has attracted significant attention as next-generation anode material owing to its high theoretical specific capacity and low potential. For enabling the practical application of Li-metal as an anode according to energy demands, suppressing dendrite growth by controlling
N J Hales et al.
Journal of medicinal chemistry, 36(24), 3853-3858 (1993-11-26)
Members of a series of 2,2'-bipyridines have been synthesized and tested as inhibitors of prolyl hydroxylase (EC 1.14.11.2). The structure-activity relationships seen with [2,2'-bipyridine]-5-carboxylic acid (4) closely resemble those of pyridine-2-carboxylic acid (2). Accordingly, [2,2'-bipyridine]-5,5'-dicarboxylic acid (11, IC50 = 0.19

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