516031
(S)-(-)-N-Z-氮杂环丙烷-2-羧酸甲酯
96%
别名:
(2S)-1,2-Aziridinedicarboxylic acid 2-methyl 1-(phenylmethyl) ester, (S)-N-Cbz-aziridine-2-carboxylic acid methyl ester, 1-Benzyl 2-methyl (S)-(−)-1,2-aziridinedicarboxylate, Methyl (S)-N-Cbz-aziridine-2-carboxylate
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所有图片(1)
About This Item
经验公式（希尔记法）:
C12H13NO4
CAS号:
分子量:
235.24
MDL编号:
UNSPSC代码:
12352005
PubChem化学物质编号:
NACRES:
NA.22
检测方案
96%
旋光性
[α]20/D −25°, c = 1 in toluene
折射率
n20/D 1.519 (lit.)
bp
160-165 °C/2 mmHg (lit.)
密度
1.19 g/mL at 25 °C (lit.)
SMILES字符串
COC(=O)C1CN1C(=O)OCc2ccccc2
InChI
1S/C12H13NO4/c1-16-11(14)10-7-13(10)12(15)17-8-9-5-3-2-4-6-9/h2-6,10H,7-8H2,1H3/t10-,13?/m0/s1
InChI key
GTZJUBQWCWZING-NKUHCKNESA-N
一般描述
Methyl (S)-(−)-N-Z-aziridine-2-carboxylate is commonly used as an electrophilic aziridination reagent in organic synthesis. It is a chiral bicyclic lactam reagent that can be used for the synthesis of chiral aziridines from alkenes. The reagent is particularly useful in the synthesis of chiral building blocks.
应用
Methyl (S)-(−)-N-Z-aziridine-2-carboxylate can be used as a reactant in the total synthesis of α-C-mannosyltryptophan (C-Man-Trp), a naturally occurring C-glycosylamino acid. It is also used in the preparation of optically active aziridine derivatives.
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves
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