所有图片(1)
About This Item
线性分子式:
C7H10(=O)2
CAS号:
分子量:
126.15
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
质量水平
检测方案
97%
折射率
n20/D 1.483 (lit.)
bp
254 °C (lit.)
密度
1.1 g/mL at 25 °C (lit.)
SMILES字符串
O=C1CCCCC(=O)C1
InChI
1S/C7H10O2/c8-6-3-1-2-4-7(9)5-6/h1-5H2
InChI key
DBOVMTXPZWVYAQ-UHFFFAOYSA-N
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves
法规信息
新产品
Evan A Sims et al.
Tetrahedron letters, 52(16), 1871-1873 (2011-06-29)
We report the large-scale synthesis of 1,3-cyclooctanedione in five steps with 29% yield. This molecule is a synthetic precurser to difluorinated cyclooctyne, which participates in a bioorthogonal copper-free click reaction with azides. The final step demonstrates the first successful application
Allen Y Hong et al.
Tetrahedron, 67(52), 10234-10248 (2012-02-22)
General catalytic asymmetric routes toward cyclopentanoid and cycloheptanoid core structures embedded in numerous natural products have been developed. The central stereoselective transformation in our divergent strategies is the enantioselective decarboxylative alkylation of seven-membered β-ketoesters to form α-quaternary vinylogous esters. Recognition
Michael additions of 1, 3-cycloalkanediones to dimethyl acety-lenedicarboxylate.
Hrnciar P, et al.
Chemical Papers, 43(1), 87-95 (1989)
Methylation of 1, 3-cyclopentanedione, 1, 3-cyclohexanedione, and 1, 3-cycloheptanedione with iodomethane in aprotic solvents in the absence and in the presence of 18-crown-6.
Sraga J and Hrnciar P.
Chemical Papers, 35(1), 119-126 (1981)
Michael addition of 1, 3-cyclopentanedione, 1, 3-cyclohexanedione and 1, 3-cycloheptanedione to 1-(X-phenyl)-2-nitroethylenes.
Hrnciar P and Culak I.
Collection of Czechoslovak Chemical Communications, 49(6), 1421-1431 (1984)
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