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About This Item
经验公式（希尔记法）:
C34H33ClN2O
CAS号:
分子量:
521.09
MDL编号:
UNSPSC代码:
12352005
PubChem化学物质编号:
NACRES:
NA.22
检测方案
85%
mp
158-161 °C (lit.)
SMILES字符串
[Cl-].OC(C1CC2CC[N+]1(CC2C=C)Cc3c4ccccc4cc5ccccc35)c6ccnc7ccccc67
InChI
1S/C34H33N2O.ClH/c1-2-23-21-36(22-31-27-11-5-3-9-25(27)19-26-10-4-6-12-28(26)31)18-16-24(23)20-33(36)34(37)30-15-17-35-32-14-8-7-13-29(30)32;/h2-15,17,19,23-24,33-34,37H,1,16,18,20-22H2;1H/q+1;/p-1
InChI key
PICKZKQBJJCSSV-UHFFFAOYSA-M
一般描述
N-(9-Anthracenylmethyl)cinchonindinium chloride can be prepared by reacting cinchonidine with 9-chloromethylanthracene.
应用
N-(9-Anthracenylmethyl)cinchonindinium chloride may be used in the preparation of O-allyl-N-(9-anthracenylmethyl)cinchonidinium bromide, a cinchona-based chiral phase-transfer catalyst (PTC).
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
法规信息
新产品
Preparation of O-Allyl-N-(9-Anthracenylmethyl) cinchonidinium Bromide as a Phase Transfer Catalyst for the Enantioselective Alkylation of Glycine Benzophenone Imine tert-Butyl Ester:(4S)-2-(Benzhydrylidenamino) pentanedioic Acid, 1-tert-Butyl Ester-5-Methyl Ester.
Corey EJ and Noe MC.
Organic Syntheses, 38-45 (2003)
Cinchona-based phase-transfer catalysts for asymmetric synthesis.
Jew SS and Park HG.
Chemical Communications (Cambridge, England), 46, 7090-7103 (2009)
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