514330
甲基锂 溶液
3.1 M in diethoxymethane
别名:
Lithium methanide, MeLi
登录 查看组织和合同定价。
选择尺寸
关于此项目
经验公式（希尔记法）:
CH3Li
化学文摘社编号:
分子量:
21.98
UNSPSC Code:
12352103
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
3587162
产品名称
甲基锂 溶液, 3.1 M in diethoxymethane
InChI
1S/CH3.Li/h1H3;
SMILES string
[Li]C
InChI key
DVSDBMFJEQPWNO-UHFFFAOYSA-N
form
liquid
concentration
3.1 M in diethoxymethane
density
0.846 g/mL at 25 °C
storage temp.
2-8°C
Quality Level
正在寻找类似产品? 访问 产品对比指南
Application
在钛酸四异丙酯存在下，以2-(2-羟基芳基)醇（HAROL）配体为催化剂，甲基锂溶液（3.1 M，溶剂为二乙氧基甲烷）可以与苯甲醛发生1,2-加成，形成 (S)-1-苯乙-1-醇。
Disclaimer
产品可能在瓶底形成固体或沉淀物。
Packaging
建议将25 mL Sure/Seal™ 瓶作为一次性瓶使用。 反复穿刺可能导致产品性能下降。
Legal Information
Sure/Seal is a trademark of Sigma-Aldrich Co. LLC
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Flam. Liq. 2 - Pyr. Liq. 1 - Skin Corr. 1B - Water-react 1
存储类别
4.2 - Pyrophoric and self-heating hazardous materials
wgk
WGK 1
flash_point_f
5.0 °F - closed cup
flash_point_c
-15 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Chiral 2-(2-hydroxyaryl) alcohols (HAROLs) with a 1, 4-diol scaffold as a new family of ligands and organocatalysts.
Dilek O, et al.
Tetrahedron, 74(2), 268-286 (2018)
Erik Selander et al.
Proceedings of the National Academy of Sciences of the United States of America, 112(20), 6395-6400 (2015-04-29)
Interactions among microscopic planktonic organisms underpin the functioning of open ocean ecosystems. With few exceptions, these organisms lack advanced eyes and thus rely largely on chemical sensing to perceive their surroundings. However, few of the signaling molecules involved in interactions
我们的科学家团队拥有各种研究领域经验，包括生命科学、材料科学、化学合成、色谱、分析及许多其他领域.
联系客户支持