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About This Item
经验公式（希尔记法）:
C10H12N2O
CAS号:
分子量:
176.22
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
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方案
95%
mp
126-130 °C (lit.)
官能团
amine
ketone
SMILES字符串
CN(C)\C=C\C(=O)c1ccccn1
InChI
1S/C10H12N2O/c1-12(2)8-6-10(13)9-5-3-4-7-11-9/h3-8H,1-2H3/b8-6+
InChI key
BWERGHWJEBQNQV-SOFGYWHQSA-N
一般描述
3-(Dimethylamino)-1-(2-pyridyl)-2-propen-1-one (1-(2′-Pyridyl)-3-dimethylamino-2-propen-1-one), an enaminone, is a hemilabile hybrid ligand. The preparation of cationic mononuclear rhodium(I) or iridium(I) complexes containing 3-(dimethylamino)-1-(2-pyridyl)-2-propen-1-one have been reported.
应用
3-(Dimethylamino)-1-(2-pyridyl)-2-propen-1-one may be used in the preparation of the 5-(heteroaryl)isoxazole derivatives, 5-(2-pyridyl)isoxazole and 3-methyl-5-(2-pyridyl)isoxazole. It may also be used to synthesize 7-(2-pyridyl)-1,2,4-triazolo[1,5-a]pyrimidine.
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
Synthesis and Antibacterial Activity of Novel 5-(heteroaryl) isoxazole Derivatives.
Rao RJR, et al.
J. Korean Chem. Soc., 55(2), 243-250 (2011)
Synthesis and Antimicrobial Activity of Novel 7-(Heteroaryl)-1,2,4-triazolo[1,5-a]-pyrimidine Derivatives.
Rao RJR, et al.
Asian Journal of Chemistry, 24(4), 1837-1837 (2012)
The rhodium and iridium co-ordination chemistry of the hemilabile hybrid ligand 1-(2'-pyridyl)-3-dimethylamino-2-propen-1-one.
Marti'nez AP, et al.
Inorgorganica Chimica Acta, 347, 86-98 (2003)
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