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线性分子式:
Al[OCH(CH3)C2H5]3
化学文摘社编号:
分子量:
246.32
UNSPSC Code:
12352103
NACRES:
NA.23
PubChem Substance ID:
EC Number:
218-871-2
Beilstein/REAXYS Number:
3910908
MDL number:
产品名称
三仲丁氧基铝, 99.99% trace metals basis
InChI key
WOZZOSDBXABUFO-UHFFFAOYSA-N
InChI
1S/3C4H9O.Al/c3*1-3-4(2)5;/h3*4H,3H2,1-2H3;/q3*-1;+3
SMILES string
CCC(C)O[Al](OC(C)CC)OC(C)CC
assay
99.99% trace metals basis
form
liquid
autoignition temp.
763 °F
expl. lim.
9.8 %
reaction suitability
core: aluminum
bp
200-206 °C/30 mmHg (lit.)
density
0.967 g/mL at 25 °C (lit.)
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Features and Benefits
已用于制备高表面积氧化铝,其中以 2,4-戊二酮(Aldrich 产品 P775-4)作为螯合剂。
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Dermal - Acute Tox. 4 Oral - Flam. Liq. 3
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
78.8 °F - closed cup
flash_point_c
26 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Flaminia Rondino et al.
Physical chemistry chemical physics : PCCP, 13(3), 818-824 (2010-12-07)
Diastereomeric adducts between (S)-1-(4-fluorophenyl)-ethanol and R and S 2-butanol, formed by supersonic expansion, have been investigated by means of a combination of mass selected resonant two-photon ionization-spectroscopy and infrared depletion spectroscopy. Chiral recognition is evidenced by the specific spectroscopic signatures
Feng Gao et al.
Journal of the American Chemical Society, 129(49), 15240-15249 (2007-11-16)
The enantioselective chemisorption of R- and S-propylene oxide has been measured either on clean Pd(111) that has been exposed to S-2-butanol at various temperatures to vary the proportion of 2-butanol and 2-butoxide species or by adsorbing S-2-butanol on oxygen-covered Pd(111)
Timothy E Morey et al.
AIDS and behavior, 17(1), 298-306 (2012-09-25)
A breath-based adherence system to document ingestion of oral medications (e.g., HAART) was investigated. Specifically, the food additive 2-butanol, which can be easily packaged with a drug, is converted via alcohol dehydrogenase to the volatile metabolite 2-butanone that rapidly appears
Saeko Shin et al.
The journal of physical chemistry. A, 110(6), 2122-2129 (2006-02-10)
The vibrational circular dichroism (VCD) spectra of (S)-(+)-2-butanol have been observed in dilute CS(2) solutions. Two strong VCD bands are assigned mainly to the OH bending modes with the aid of quantum chemical calculations. The calculated VCD spectra corresponding to
Uri Cogan et al.
Chirality, 24(7), 500-505 (2012-05-10)
Supramolecular chiral assemblies of R(-) and S(+) 2-butanol, in their neat form or when dissolved in their nonchiral isomer isobutanol, were evaluated by isothermal titration calorimetry (ITC) ensuing mixing. Dilution of 0.5 M solution of R(-) 2-butanol in isobutanol into
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