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Merck
CN

51053

Sigma-Aldrich

1-乙基-3-甲基咪唑乙酸酯

≥95.0% (HPLC)

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别名:
EMIM Ac
经验公式(希尔记法):
C8H14N2O2
分子量:
170.21
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

质量水平

检测方案

≥95.0% (HPLC)

来源

Switzerland origin

mp

>30 °C (product can occur as an undercooled melt)

密度

1.101 g/cm3 at 20 °C

SMILES字符串

CC([O-])=O.CCn1cc[n+](C)c1

InChI

1S/C6H11N2.C2H4O2/c1-3-8-5-4-7(2)6-8;1-2(3)4/h4-6H,3H2,1-2H3;1H3,(H,3,4)/q+1;/p-1

InChI key

XIYUIMLQTKODPS-UHFFFAOYSA-M

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一般描述

1-乙基-3-甲基咪唑乙酸酯([EMIM][Ac])是一种与水混溶的环保型咪唑离子液体。它显示出良好的纤维素溶解能力。[·EMIM Ac]对梭菌恶臭假单胞菌生长影响的研究显示出类似激素的作用。据报道,无机盐的加入提高了其离子性。我们还对纤维素在活性炭中的热稳定性进行了研究。

应用

1-乙基-3-甲基咪唑乙酸盐适用于纤维素与酰氯、三苯甲基氯和甲苯磺酰氯的均相转化中作为纤维素溶剂。它可用作合成接枝有聚苯乙烯(淀粉-g-PS)的淀粉和环境友好纤维素膜的共聚物的溶剂。

象形图

Exclamation mark

警示用语:

Warning

危险声明

危险分类

Acute Tox. 4 Oral - Skin Irrit. 2 - Skin Sens. 1B

WGK

WGK 3

个人防护装备

Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)


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Interactions of Ionic Liquids with Polysaccharides 1. Unexpected Acetylation of Cellulose with 1-Ethyl-3-methylimidazolium Acetate.
Kohler S, et al.
Macromolecular Rapid Communications, 28(24), 2311-2317 (2007)
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Carbohydrate polymers, 121, 71-78 (2015-02-11)
With the serious "white pollution" resulted from the non-biodegradable plastic films, considerable attention has been directed toward the development of renewable and biodegradable cellulose-based film materials as substitutes of petroleum-derived materials. In this study, environmentally friendly cellulose films were successfully
Anne Michud et al.
Carbohydrate polymers, 117, 355-363 (2014-12-17)
The thermal stability of cellulose in the ionic liquid (IL) 1-ethyl-3-methylimidazolium acetate, [emim]OAc was investigated. For this purpose, Eucalyptus urugrandis prehydrolysis kraft pulp was first dissolved in [emim]OAc by means of a vertical kneader and then stored at three different
Yongjun Men et al.
Carbohydrate polymers, 121, 348-354 (2015-02-11)
The copolymer of starch grafted with polystyrene (starch-g-PS) was synthesized with high grafting percentage by utilizing the ionic liquid 1-ethyl-3-methylimidazolium acetate ([EMIM]Ac) as solvent and potassium persulfate as initiator. The effect of various parameters upon the polymerization were studied including:

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