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质量水平
检测方案
97%
mp
110-114 °C (lit.)
SMILES字符串
O=C(c1ccccc1)c2ccc(cc2)C#N
InChI
1S/C14H9NO/c15-10-11-6-8-13(9-7-11)14(16)12-4-2-1-3-5-12/h1-9H
InChI key
YSZWJJANSNFQMM-UHFFFAOYSA-N
一般描述
4-Cyanobenzophenone is a benzophenone derivative that can be prepared by treating 4-cyanobenzoyl chloride with benzene. Its reduction under electrochemical condition led to the formation of 4-t-butyl-benzophenone and 1-(4-cyanophenyl)-2,2-dimthyl-1-phenylpropan-1-ol. Its efficiency as triplet sensitizer for norbornadiene(N)→quadriciane(Q) and Q→N photoisomerization has been assessed.
警示用语:
Warning
危险分类
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
法规信息
新产品
Electrochemically induced aromatic nucleophilic substitution.
Journal of the American Chemical Society, 100(5), 1506-1510 (1978)
Mechanistic approach to the sensitization process of aromatic ketones in the isomerization between norbornadiene and quadricyclane.
Bulletin of the Chemical Society of Japan, 60(8), 2937-2943 (1987)
Electrochemical t-Butylation of Some Aromatic Ketones.
Acta Chemica Scandinavica. Series B, 33, 735-741 (1979)
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