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Merck
CN

510068

Sigma-Aldrich

Raney®-镍

W.R. Grace and Co. Raney® 3202, slurry, in H2O, active catalyst

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别名:
海绵镍
线性分子式:
AlNi
CAS号:
MDL编号:
UNSPSC代码:
12352300
PubChem化学物质编号:
NACRES:
NA.22

质量水平

形式

slurry

反应适用性

core: nickel
reagent type: catalyst

制造商/商品名称

W.R. Grace and Co. Raney® 3202

浓度

in H2O

SMILES字符串

[Al].[Ni]

InChI

1S/Al.Ni

InChI key

NPXOKRUENSOPAO-UHFFFAOYSA-N

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应用

Useful as a selective reducing agent for hydrogenation of organic compounds

法律信息

Raney is a registered trademark of W.R. Grace & Co.-Conn.

警示用语:

Danger

危险分类

Carc. 2 - Pyr. Liq. 1 - Skin Sens. 1 - STOT RE 1

WGK

WGK 2

闪点(°F)

Not applicable

闪点(°C)

Not applicable

法规信息

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Nitrile reduction in the presence of Boc-protected amino groups by catalytic hydrogenation over palladium-activated Raney-nickel.
B Klenke et al.
The Journal of organic chemistry, 66(7), 2480-2483 (2001-04-03)
Barrero, A. F.; Alvarez-Manzaneda, E. J. et al.
Synthesis, 197-197 (2000)
Tsukinoki, T.; Kanda, T.
Tetrahedron Letters, 41, 5865-5865 (2000)
Toth, M.; Somsak, L.,
Tetrahedron Letters, 42, 2723-2723 (2001)
S M Marchan et al.
The European journal of prosthodontics and restorative dentistry, 21(1), 24-28 (2013-05-21)
Posterior resin bonded cast metal restorations (adhesive onlays) were used in a variety of clinical scenarios including: management of tooth wear and cracked tooth, as retainers for fixed bridge work, for correction of the occlusal plane and in providing cuspal

商品

Nickel complexes catalyze various synthetic reactions like oxidative addition, C-H activation, and cross-coupling.

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