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About This Item
经验公式（希尔记法）:
C6H6BrNZn
CAS号:
分子量:
237.41
MDL编号:
UNSPSC代码:
12352103
PubChem化学物质编号:
NACRES:
NA.22
浓度
0.5 M in THF
密度
0.959 g/mL at 25 °C
储存温度
2-8°C
SMILES字符串
Cc1ccc([Zn]Br)nc1
InChI
1S/C6H6N.BrH.Zn/c1-6-3-2-4-7-5-6;;/h2-3,5H,1H3;1H;/q;;+1/p-1
InChI key
ZWOPKPFXOHYOBO-UHFFFAOYSA-M
应用
5-Methyl-2-pyridylzinc bromide can be used as a substrate:
- In the Pd-catalyzed C-C bond-forming reactions with 3-iodothiophene.
- In the Pd-catalyzed synthesis of 5-heteroaryl- and 5-aryl-2-furaldehydes by reacting with 5-bromo-2-furaldehyde.
法律信息
Rieke® Metals, Inc. 产品 ®Rieke Metals, Inc. 的注册商标
警示用语：
Danger
危险分类
Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
补充剂危害
WGK
WGK 3
闪点(°F)
closed cup
闪点(°C)
closed cup
法规信息
新产品
2-Pyridyl and 3-pyridylzinc bromides: direct preparation and coupling reaction
Kim S and Rieke RD
Tetrahedron, 66(17), 3135-3146 (2010)
A convenient synthesis of 5-aryl-and 5-heteroaryl-2-furaldehydes by the cross-coupling reaction of organozincs
Kim S and Rieke RD
Tetrahedron Letters, 51(19), 2657-2659 (2010)
Seung-Hoi Kim et al.
The Journal of organic chemistry, 78(5), 1984-1993 (2012-10-19)
Facile synthetic routes for the preparation of a wide range of 5-substituted 2-furaldehydes have been revealed. They were accomplished through either Pd-catalyzed cross-coupling reaction of various aryl- and heteroarylzinc halides with 5-bromo-2-furaldehyde or utilization of a new organozinc reagent, 5-(1,3-dioxolan-2-yl)-2-furanylzinc
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