质量水平
检测方案
96%
折射率
n20/D 1.421 (lit.)
bp
112-114 °C (lit.)
密度
0.838 g/mL at 25 °C (lit.)
SMILES字符串
OCCC=C
InChI
1S/C4H8O/c1-2-3-4-5/h2,5H,1,3-4H2
InChI key
ZSPTYLOMNJNZNG-UHFFFAOYSA-N
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一般描述
3-丁烯-1-醇是一种高烯丙醇，可以通过使用铈催化剂脱水1,4-丁二醇来制备。用红外光谱和1H NMR光谱数据研究了3-丁烯-1-醇的分子内氢键。对其微波光谱进行了记录和分析。研究了钛-有机铝体系3-丁烯-1-醇的烷基化反应。据报告，其气相生成焓为-147.3 ± 1.8kJ mol-1。
应用
用于研究锰催化的烯烃氢肼化。也用于研究炔丙基乙酸酯转化为氯化铁催化的醚。
警示用语：
Warning
危险分类
Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
WGK
WGK 3
闪点(°F)
closed cup
闪点(°C)
closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
Jérôme Waser et al.
Journal of the American Chemical Society, 128(35), 11693-11712 (2006-08-31)
The discovery, study, and implementation of the Co- and Mn-catalyzed hydrohydrazination and hydroazidation reactions of olefins are reported. These reactions are equivalent to direct hydroaminations of C-C double bonds with protected hydrazines or hydrazoic acid but are based on a
Synlett, 2278-2278 (2006)
The conformational composition of 3-buten-1-ol, the importance of intramolecular hydrogen bonding.
Bakke JM and Bjerkeseth LH.
Journal of Molecular Structure, 470(3), 247-263 (1998)
Transition metal promoted alkylations of unsaturated alcohols: the methylation and ethylation of 3-buten-1-ol using titanium tetrachloride-organoaluminum systems.
Youngblood AV, et al.
Journal of Organometallic Chemistry, 146(3), 221-228 (1978)
Microwave spectrum, intramolecular hydrogen bond, dipole moment and centrifugal distortion of 3-buten-1-ol.
Marstokk KM and Mollendal H.
Acta Chemica Scandinavica, Series A: Physical and Inorganic Chemistry, 35(6), 395-401 (1981)
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