推荐产品
质量水平
方案
≥95.0% (GC)
折射率
n20/D 1.415
n20/D 1.415
官能团
allyl
ester
SMILES字符串
COC(=O)CCC=C
InChI
1S/C6H10O2/c1-3-4-5-6(7)8-2/h3H,1,4-5H2,2H3
InChI key
SHCSFZHSNSGTOP-UHFFFAOYSA-N
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一般描述
4-戊烯酸甲酯是由1-戊烯酸与甲醇酯化而制得的不饱和甲酯。它通过丙酮引发的光化学反应与甲酰胺进行酰胺化,形成1:1加合物。已经报告了4-戊烯酸甲酯与不同的Mo(VI)亚烷基复合物的复分解反应。它在使用RuII(H20)6(tos)2(tos =对甲苯磺酸盐)作为催化剂的 exo,exo-5,6-双(甲氧基甲基)-7-氧杂双环[2.2.1]庚-2-烯聚合过程中充当链转移剂。
警示用语:
Warning
危险声明
危险分类
Eye Irrit. 2 - Flam. Liq. 3
储存分类代码
3 - Flammable liquids
WGK
WGK 3
闪点(°F)
84.2 °F - closed cup
闪点(°C)
29 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
Coupling of terminal olefins by molybdenum (VI) imido alkylidene complexes.
Organometallics, 13(2), 635-639 (1994)
Chain transfer during the aqueous ring-opening metathesis polymerization of 7-oxanorbornene derivatives.
Macromolecules, 26(18), 4742-4747 (1993)
The Light-Induced Amidation of Terminal Olefins1.
The Journal of Organic Chemistry, 29(7), 1855-1859 (1964)
ChemSusChem, 12(12), 2628-2636 (2019-04-18)
The need for more sustainable products and processes has led to the use of new methodologies with low carbon footprints. In this work, an efficient tandem process is demonstrated for the liquid-phase catalytic upgrading of lignocellulosic biomass-derived γ-valerolactone (GVL) with
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