496383
1,10-菲咯啉-5,6-二酮
97%
别名:
Stahl phd 氧化剂, phd
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关于此项目
经验公式（希尔记法）:
C12H6N2O2
化学文摘社编号:
分子量:
210.19
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
质量水平
方案
97%
mp
260 °C (dec.) (lit.)
官能团
ketone
SMILES字符串
O=C1C(=O)c2cccnc2-c3ncccc13
InChI
1S/C12H6N2O2/c15-11-7-3-1-5-13-9(7)10-8(12(11)16)4-2-6-14-10/h1-6H
InChI key
KCALAFIVPCAXJI-UHFFFAOYSA-N
一般描述
1,10-菲咯啉-5,6-二酮 (phendio) 形式的 Cu (II) 和 Ag (I) phendio 复合物，显示出有效的抗真菌和抗癌活性。转换金属苯二酚配合物对玻碳电极进行修饰，使 NADH 在低过电位下发生催化氧化。
应用
1,10-菲咯啉-5,6-二酮可用于与早期转换金属离子的均金属和杂金属配合物的制备。
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
Tetsuaki Fujihara et al.
Dalton transactions (Cambridge, England : 2003), (4)(4), 645-652 (2004-07-15)
Syntheses and pH dependent electrochemical properties of aqua-ruthenium(II) complexes, [Ru(trpy)(PDA-N,N')(OH2)](ClO4)2 ([1](ClO4)2) and [Ru(trpy)(PD-N,N')(OH2)](ClO4)2 ([2](ClO4)2) (trpy = 2,2':6',2''-terpyridine, PDA = 6-acetonyl-6-hydroxy-1,10-phenanthroline-5-one, PD = 1,10-phenanthroline-5,6-dione) are presented. Treatment of [Ru(trpy)(PD-N,N')Cl](PF6) with AgClO4 in a mixed solvent of acetone and H2O selectively produced
Aleksandra Pinczewska et al.
Journal of the American Chemical Society, 134(43), 18022-18033 (2012-10-11)
We report the combinatorial preparation and high-throughput screening of a library of modified electrodes designed to catalyze the oxidation of NADH. Sixty glassy carbon electrodes were covalently modified with ruthenium(II) or zinc(II) complexes bearing the redox active 1,10-phenanthroline-5,6-dione (phendione) ligand
Sudeshna Roy et al.
ChemMedChem, 3(9), 1427-1434 (2008-06-10)
Phenanthroline derivatives are of interest due to their potential activity against cancer, and viral, bacterial, and fungal infections. In a search for highly specific antitumor and antibacterial compounds, we report the activities of 1,10-phenanthroline-5,6-dione (phendione or L(1)), dipyrido[3,2-a:2',3'-c]phenazine (dppz or
Xuyan Mao et al.
The Analyst, 136(2), 293-298 (2010-10-20)
To improve the electrocatalytic activities of carbon nanotubes (CNT) towards the oxidation of nicotinamide adenine dinucleotide (NADH), we derive them with a redox mediator, 1,10-phenanthroline-5,6-dione (PD), by the noncovalent functionalization method. The redox carbon nanotubes (PD/CNT/GC) show excellent electrocatalytic activities
Electrocatalytic oxidation of NADH at glassy carbon electrodes modified with transition metal complexes containing 1, 10-phenanthroline-5, 6-dione ligands.
Wu Q, et al.
Analytical Chemistry, 68(20), 3688-3696 (1996)
相关内容
he Stahl Lab focuses on the development of catalysts and catalytic reactions for selective oxidation of organic molecules, with particular emphasis on aerobic oxidation reactions.
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