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质量水平
方案
97%
mp
260 °C (dec.) (lit.)
官能团
ketone
SMILES字符串
O=C1C(=O)c2cccnc2-c3ncccc13
InChI
1S/C12H6N2O2/c15-11-7-3-1-5-13-9(7)10-8(12(11)16)4-2-6-14-10/h1-6H
InChI key
KCALAFIVPCAXJI-UHFFFAOYSA-N
一般描述
1,10-菲咯啉-5,6-二酮 (phendio) 形式的 Cu (II) 和 Ag (I) phendio 复合物,显示出有效的抗真菌和抗癌活性。转换金属苯二酚配合物对玻碳电极进行修饰,使 NADH 在低过电位下发生催化氧化。
应用
1,10-菲咯啉-5,6-二酮可用于与早期转换金属离子的均金属和杂金属配合物的制备。
警示用语:
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
Electrocatalytic oxidation of NADH at glassy carbon electrodes modified with transition metal complexes containing 1, 10-phenanthroline-5, 6-dione ligands.
Analytical Chemistry, 68(20), 3688-3696 (1996)
Journal of inorganic biochemistry, 103(3), 396-400 (2009-01-13)
Three new solid complexes have been synthesized by the reaction of rare earth(III) nitrate with the first ligand curcumin (HL) and the second ligand 1,10-phenanthroline-5,6-dione (L') in alcohol solution (pH=6.5-7.0). The composition of the complexes has been characterized by elemental
1, 10-Phenanthroline-5, 6-dione as a building block for the synthesis of homo-and heterometallic complexes.
Inorgorganica Chimica Acta, 330(1), 136-142 (2002)
Biosensors & bioelectronics, 13(3-4), 319-332 (1998-06-27)
Various strategies based on the use of chemically modified electrodes for the development of amperometric biosensors are described. Particular emphasis is placed on materials capable of catalyzing the oxidation of NADH and coupling these with enzymatic activities for biosensor construction.
The Analyst, 136(1), 148-154 (2010-10-20)
The first probe for the fluorogenic determination of acetyl phosphate (AcP), (bpy)(2)Ru(1,10-phenanthroline-5,6-dione dioxime) (RuPDO), was prepared and its reaction with AcP was studied in detail. The emission of the weakly luminescent RuPDO is red shifted and strongly enhanced upon reaction
相关内容
he Stahl Lab focuses on the development of catalysts and catalytic reactions for selective oxidation of organic molecules, with particular emphasis on aerobic oxidation reactions.
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