所有图片(1)
About This Item
经验公式（希尔记法）:
C8H5BrS
CAS号:
分子量:
213.09
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
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质量水平
方案
95%
折射率
n20/D 1.668 (lit.)
沸点
269 °C/752.5 mmHg (lit.)
密度
1.629 g/mL at 25 °C (lit.)
官能团
bromo
SMILES字符串
Brc1csc2ccccc12
InChI
1S/C8H5BrS/c9-7-5-10-8-4-2-1-3-6(7)8/h1-5H
InChI key
SRWDQSRTOOMPMO-UHFFFAOYSA-N
一般描述
3-Bromothianaphthene is a heteroaryl halide. It undergoes Suzuki-Miyaura reaction with phenylboronic acid (PBA) or 3-thienylboronic acid in the presence of a novel heterogeneous Pd catalyst [Pd@PDEB, PDEB=poly(1,3-diethynylbenzene)]. The substitution reaction of 3-bromothianaphthene with piperidine to form 3-piperidinothianaphthene as the major product has been reported.
应用
3-Bromothianaphthene may be used in the synthesis of (benzo[b]thiophen-3-yl)trimethylstannane.
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves, type N95 (US)
法规信息
新产品
Reusable, Highly Active Heterogeneous Palladium Catalyst by Convenient Self-Encapsulation Cross-Linking Polymerization for Multiple Carbon-Carbon Cross-Coupling Reactions at ppm to ppb Palladium Loadings.
Dong Z and Ye Z.
Advanced Synthesis & Catalysis, 356(16), 3401-3414 (2014)
Reactions of bromothianaphthenes with piperidine. Reinvestigation.
Reinecke MG, et al.
The Journal of Organic Chemistry, 38(7), 1365-1367 (1973)
Electronic influence of the thienyl sulfur atom on the oligomerization of ethylene by cobalt (II) 6-(thienyl)-2-(imino) pyridine catalysis.
Bianchini C, et al.
Organometallics, 26(3), 726-739 (2007)
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