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质量水平
方案
98%
折射率
n20/D 1.557 (lit.)
沸点
212 °C (lit.)
密度
0.958 g/mL at 25 °C (lit.)
官能团
amine
SMILES字符串
CNc1ccc(C)cc1
InChI
1S/C8H11N/c1-7-3-5-8(9-2)6-4-7/h3-6,9H,1-2H3
InChI key
QCIFLGSATTWUQJ-UHFFFAOYSA-N
一般描述
N-Methyl-p-toluidine is an aromatic secondary amine. It forms social isomers when encapsulated with a molecule of chloroform or benzene in a cylindrical capsule. 2-amino-4,6-dichloropyrimidine-5-carbaldehyde undergoes mono-amination with N-methyl-p-toluidine to form a precursor for the preparation of pyrazolo[3,4-d]pyrimidines. It annelates with dimethyl acetylenedicarboxylate via formation of toluidine radical cation intermediate.
警示用语：
Danger
危险分类
Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Chronic 3 - STOT RE 2
储存分类代码
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGK
WGK 3
闪点(°F)
183.0 °F - closed cup
闪点(°C)
83.89 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Microwave-assisted synthesis of pyrazolo [3,4-d] pyrimidines from 2-amino-4, 6-dichloropyrimidine-5-carbaldehyde under solvent-free conditions.
Quiroga J, et al.
Tetrahedron Letters, 49(20), 3257-3259 (2008)
Palladium-promoted aromatic annelation with acetylene dicarboxylates.
Sakakibara T, et al.
Chemistry Letters (Jpn), 15(5), 797-800 (1986)
Simultaneous encapsulation: molecules held at close range.
Rebek J.
Angewandte Chemie (International Edition in English), 44(14), 2068-2078 (2005)
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