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About This Item
线性分子式:
CH3OOCCH2CH=CHCOOCH3
CAS号:
分子量:
158.15
Beilstein:
1724169
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
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方案
≥95.0% (GC)
折射率
n20/D 1.452
密度
1.124 g/mL at 20 °C (lit.)
官能团
ester
SMILES字符串
COC(=O)C\C=C\C(=O)OC
InChI
1S/C7H10O4/c1-10-6(8)4-3-5-7(9)11-2/h3-4H,5H2,1-2H3/b4-3+
InChI key
SKCGFFOFYXLNCG-ONEGZZNKSA-N
一般描述
Dimethyl glutaconate, also known as dimethyl 2-pentenoate, is a diester. It reacts with salicaldehyde in the presence of piperidine to form a coumarin-fused electron deficient diene.
应用
Dimethyl glutaconate may be used in the synthesis of:
- dimethyl 3-[(Z)-1-propenyl]glutarate
- phenanthridinone derivatives
- substituted benzenes
组分
组成：~83% 反式 + ~17% 顺式
危险声明
预防措施声明
危险分类
Aquatic Chronic 3
储存分类代码
10 - Combustible liquids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
Electron Deficient Dienes. 2. One Step Synthesis of a Coumarin-Fused Electron Deficient Diene and its Inverse Electron Demand Diels-Alder Reactions with Enamines.
Bodwell GJ, et al.
Synlett, 4, 477-479 (1999)
One-Pot Synthesis of Phenanthridinones by Using a Base-Catalyzed/Promoted Bicyclization of a, ?-Unsaturated Carbonyl Compounds with Dimethyl Glutaconate.
Li L, et al.
European Journal of Organic Chemistry, 2015(22), 4892- 4899 (2015)
A convenient method for the preparation of 3-substituted glutarate diesters.
Leotta III, et al.
The Journal of Organic Chemistry, 59(7), 1946-1946 (1994)
Base-Catalyzed Efficient Tandem [3+3] and [3+2+1] Annulation-Aerobic Oxidative Benzannulations.
Diallo A, et al.
Organic Letters, 14(22), 5776-5779 (2012)
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