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方案
98%
mp
58-61 °C (lit.)
SMILES字符串
N#CCCOc1ccccc1
InChI
1S/C9H9NO/c10-7-4-8-11-9-5-2-1-3-6-9/h1-3,5-6H,4,8H2
InChI key
IXAUFLAHUXISCH-UHFFFAOYSA-N
一般描述
3-Phenoxypropionitrile is an aryl nitrile that can be synthesized by the reaction of acrylonitrile with phenol, catalyzed by (IPr)Cu(OPh) (IPr=1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene; Ph=phenyl).
应用
3-Phenoxypropionitrile may be used as a starting material in the synthesis of a phenol novolak-type polymer.
警示用语：
Warning
危险分类
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral
储存分类代码
10 - Combustible liquids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Formaldehyde polymers, 28. Synthesis of a high molecular weight novolak-type Polymer.
Ninagawa A and Matsuda H.
Makromol. Chem., Rapid Commun., 2(6-7), 449-452 (1981)
Anti-Markovnikov NH and OH additions to electron-deficient olefins catalyzed by well-defined Cu (I) anilido, ethoxide, and phenoxide systems.
Munro-Leighton C, et al.
Journal of the American Chemical Society, 128(5), 1446-1447 (2006)
Yusuke Yamamoto et al.
The Journal of toxicological sciences, 44(9), 585-600 (2019-09-03)
Amino acid derivative reactivity assay (ADRA) has previously been developed as an alternative method to direct peptide reactivity assay (DPRA) to evaluate key event 1 in skin sensitization mechanisms. However, when using alternative methods for skin sensitization, integrated approaches to
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