所有图片(2)
About This Item
线性分子式:
C6H5CH2OCH2COCH3
CAS号:
分子量:
164.20
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
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方案
90%
杂质
3% (benzyloxy)acetic acid
3% benzyl alcohol
折射率
n20/D 1.512 (lit.)
沸点
259 °C (lit.)
密度
1.04 g/mL at 25 °C (lit.)
官能团
ether
ketone
phenyl
SMILES字符串
CC(=O)COCc1ccccc1
InChI
1S/C10H12O2/c1-9(11)7-12-8-10-5-3-2-4-6-10/h2-6H,7-8H2,1H3
InChI key
YHMRKVGUSQWDGZ-UHFFFAOYSA-N
一般描述
Benzyloxyacetone (α-Benzyloxyacetone) is an α-substituted acetone. It undergoes direct aldol reaction with 4-nitrobenzaldehyde in the presence of (S)-BINAM-L-prolinamide/benzoic acid to form predominantly the syn-diasteroisomer.
应用
Benzyloxyacetone (1-Benzyloxy-2-propanone) may be used in the synthesis of:
- 7-benzyloxy-6-methyl-5-hepten-1-yne
- (Z)-2-methylhept-2-en-6-yn-1-o1
- (S)-(+)-1,2-propanediol, 1-benzyl ether
储存分类代码
10 - Combustible liquids
WGK
WGK 3
闪点(°F)
230.0 °F - closed cup
闪点(°C)
110 °C - closed cup
个人防护装备
Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)
从最新的版本中选择一种：
分析证书(COA)
Lot/Batch Number
Synthesis and biological evaluation of L-and D-configurations of 2',3'-dideoxy-4'-C-methyl-3'-oxacytidine analogues.
Liu MC, et al.
Bioorganic & Medicinal Chemistry Letters, 11(17), 2301-2304 (2001)
A stereoselective formation of (Z)-2-methyl-2-alkenol by the wittig reaction: its application to a synthesis of nerylacetone and (Z,Z)-farnesylacetone.
Sato K, et al.
Chemistry Letters (Jpn), 10(12), 1711-1714 (1981)
Cis selective wittig olefination of a-alkoxy ketones and its application to the stereoselective synthesis of plaunotol.
Inoue S, et al.
Bulletin of the Chemical Society of Japan, 63(6), 1629-1635 (1990)
Stereochemical control of bakers' yeast mediated reduction of a protected 2-hydroxy ketone.
Manzocchi A, et al.
The Journal of Organic Chemistry, 53(18), 4405-4407 (1988)
Highly selective direct aldol reaction organocatalyzed by (S)-BINAM-L-prolinamide and benzoic acid using a-chalcogen-substituted ketones as donors.
Guillena G, et al.
ARKIVOC (Gainesville, FL, United States), 4, 260-269 (2007)
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