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483869

Sigma-Aldrich

5-(三氟甲基)二苯并噻吩鎓四氟硼酸盐

97%

别名:

S-(三氟甲基)二苯并噻吩嗡四氟硼酸盐, 梅本试剂

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About This Item

经验公式（希尔记法）:
C13H8BF7S
CAS号:
131880-16-5
分子量:
340.07
MDL编号:
MFCD01073545
UNSPSC代码:
12352101
PubChem化学物质编号:
24871922
NACRES:
NA.22

质量水平

100

方案

97%

mp

162-164 °C (lit.)

官能团

fluoro

SMILES字符串

F[B-](F)(F)F.FC(F)(F)[S+]1c2ccccc2-c3ccccc13

InChI

1S/C13H8F3S.BF4/c14-13(15,16)17-11-7-3-1-5-9(11)10-6-2-4-8-12(10)17;2-1(3,4)5/h1-8H;/q+1;-1

InChI key

VTVISWLINKWMQZ-UHFFFAOYSA-N

相关类别

应用

  • Pd（II）-催化的三氟甲基化
  • 铜催化的芳基硼酸三氟甲基化反应（以三甲吡啶为三氟甲基化试剂）
  • 芳烃的钯催化亲电邻位三氟甲基化

立体选择性制备用于
  • 铜催化末端烯烃三氟甲基化合成三氟甲基取代烯烃
  • 钯催化的 α-甲基丙烯分子内脱羧反应-三氟甲基 β-酮酸酯

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Gloves, type N95 (US)

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
MKCT4911
MKCR9433
MKCN8985
MKCM0995
MKCH9459

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Construction of Trifluoromethyl-Bearing Quaternary Carbon Centers by Intramolecular Decarboxylative Allylation of α-Trifluoromethyl β-Keto Esters
Shibata, N.; et al.
Advanced Synthesis & Catalysis, 353, 2037-2041 (2011)
Jun Xu et al.
Chemical communications (Cambridge, England), 47(14), 4300-4302 (2011-03-08)
A copper-catalyzed process for trifluoromethylation of aryl, heteroaryl, and vinyl boronic acids has been developed. The reaction is conducted under mild conditions and shows tolerance to moisture and a variety of functional groups.
Jun Xu et al.
Journal of the American Chemical Society, 133(39), 15300-15303 (2011-09-15)
An unprecedented type of reaction for Cu-catalyzed trifluoromethylation of terminal alkenes is reported. This reaction represents a rare instance of catalytic trifluoromethylation through C(sp(3))-H activation. It also provides a mechanistically unique example of Cu-catalyzed allylic C-H activation/functionalization. Both experimental and
Xisheng Wang et al.
Journal of the American Chemical Society, 132(11), 3648-3649 (2010-02-27)
A Pd(II)-catalyzed C-H activation/trifluoromethylation of arenes with an electrophilic trifluoromethylation reagent using diverse heterocycle directing groups is reported. The presence of trifluoroacetic acid is crucial for this catalytic reaction.
Xing-Guo Zhang et al.
Journal of the American Chemical Society, 134(29), 11948-11951 (2012-07-12)
A Pd(II)-catalyzed trifluoromethylation of ortho C-H bonds with an array of N-arylbenzamides derived from benzoic acids is reported. N-Methylformamide has been identified as a crucial promoter of C-CF(3) bond formation from the Pd center. X-ray characterization of the C-H insertion

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