483532
4-(二甲基氨基)苯硼酸
≥95.0%
别名:
4-(N,N-Dimethylamino)phenylboronic acid, 4-N,N-Dimethylaminobenzeneboronic acid, 4-N,N-Dimethylphenylboronic acid, 4-Dimethylaminobenzeneboronic acid, p-(Dimethylamino)-benzeneboronic acid, [4-(Dimethylamino)phenyl-1-yl]boronic acid, [4-(Dimethylamino)phenyl]boric acid
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所有图片(1)
About This Item
线性分子式:
(CH3)2NC6H4B(OH)2
CAS号:
分子量:
165.00
MDL编号:
UNSPSC代码:
12352103
PubChem化学物质编号:
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方案
≥95.0%
mp
227 °C (lit.)
SMILES字符串
CN(C)c1ccc(cc1)B(O)O
InChI
1S/C8H12BNO2/c1-10(2)8-5-3-7(4-6-8)9(11)12/h3-6,11-12H,1-2H3
InChI key
RIIPFHVHLXPMHQ-UHFFFAOYSA-N
应用
作为试剂用于以下反应
试剂用于制备
- Suzuki-Miyaura交叉偶联反应
- 镍（Ni）催化的Suzuki-Miyaura交叉偶联反应
- 铑（Rh）催化的不对称加成反应
- 钯 (Pd) 催化的C-OH键激活
试剂用于制备
- 推拉式芳基乙烯基噻嗪发色团
- 带末端推挽取代的螺旋邻苯撑低聚物
- 海藻酸钠负载的阳离子-Pd纳米凝胶作为Suzuki-Miyaura 交叉偶联反应的催化剂
- 用于染料敏化太阳能电池的有机染料
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
10 - Combustible liquids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Jian He et al.
Organic & biomolecular chemistry, 10(17), 3398-3405 (2012-03-17)
ortho-Phenylenes are an emerging class of helical oligomers and polymers. We have synthesized a series of push-pull-substituted o-phenylene oligomers (dimethylamino/nitro) up to the octamer. Conformational analysis of the hexamer using a combination of low-temperature NMR spectroscopy and ab initio predictions
Mamoru Tobisu et al.
Journal of the American Chemical Society, 133(48), 19505-19511 (2011-10-26)
Two protocols for the nickel-catalyzed cross-coupling of aryl fluorides with aryl boronic esters have been developed. The first employs metal fluoride cocatalysts, such as ZrF(4) and TiF(4), which enable Suzuki-Miyaura reactions of aryl fluorides bearing electron-withdrawing (ketones, esters, and CF(3))
Feng Cai et al.
Journal of the American Chemical Society, 133(45), 18066-18069 (2011-10-07)
We demonstrate that allenes, chiral 1,2-dienes, appended with basic functionality can serve as ligands for transition metals. We describe an allene-containing bisphosphine that, when coordinated to Rh(I), promotes the asymmetric addition of arylboronic acids to α-keto esters with high enantioselectivity.
Rapid access to 4-substituted-pyrones and 2(5H)-furanones via a palladium-catalyzed C-OH bond activation
Hu, Y.; et al.
Tetrahedron, 67, 7258-7262 (2011)
Organic dyes incorporating the cyclopentadithiophene moiety for efficient dye-sensitized solar cells
Cheng, X.; et al.
Dyes and Pigments, 92, 1292-1299 (2012)
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