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Merck
CN

482099

Sigma-Aldrich

环丙基甲醇

≥99.5%

别名:

CPMO, 环丙烷甲醇, 环丙甲醇, 羟甲基环丙烷

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About This Item

线性分子式:
C3H5CH2OH
CAS号:
分子量:
72.11
Beilstein:
1846846
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

质量水平

检测方案

≥99.5%

折射率

n20/D 1.431 (lit.)

bp

123-124 °C/738 mmHg (lit.)

密度

0.89 g/mL at 25 °C (lit.)

SMILES字符串

OCC1CC1

InChI

1S/C4H8O/c5-3-4-1-2-4/h4-5H,1-3H2

InChI key

GUDMZGLFZNLYEY-UHFFFAOYSA-N

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一般描述

羟甲基环丙烷(环丙基甲醇,CPMO)是一种麻醉剂。经报道了环丙烷甲醇与炔烃的偶联反应,生成取代的烯丙基醇。记录了CPMO的微波光谱。其旋转常数和偶极矩已经确定。

应用

环丙烷乙醇可用于制备:
  • 环丙烷甲醛
  • 环丙基甲磺酸盐
  • 二苄基环丙基甲基磷酸盐

象形图

Flame

警示用语:

Warning

危险声明

危险分类

Flam. Liq. 3

WGK

WGK 1

闪点(°F)

95.0 °F

闪点(°C)

35 °C

个人防护装备

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

危险化学品

分析证书(COA)

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D E Raines et al.
Anesthesiology, 78(5), 918-927 (1993-05-01)
N-alkanols containing up to 12 carbons are anesthetic; however, those with more than 12 carbons are not. This phenomenon has been termed cutoff. Lipid disordering theories of anesthesia suggest that cutoff occurs because the alkyl chains of long-chain alcohols approach
Surbhi Soni et al.
Chirality, 30(1), 85-94 (2017-10-25)
A profoundly time-efficient chemoenzymatic method for the synthesis of (S)-3-(4-chlorophenoxy)propan-1,2-diol and (S)-1-chloro-3-(2,5-dichlorophenoxy)propan-2-ol, two important pharmaceutical intermediates, was successfully developed using Pseudomonas fluorescens lipase (PFL). Kinetic resolution was successfully achieved using vinyl acetate as acylating agent, toluene/hexane as solvent, and reaction
Nickel-Catalyzed Redox-Economical Coupling of Alcohols and Alkynes to Form Allylic Alcohols.
Nakai K, et al.
Journal of the American Chemical Society, 136(22), 7797-7800 (2014)
Cyclopropylmethyl dihydrogen phosphate. Preparation and use in the phosphorylation of nucleosides.
Schoffstall AM.
The Journal of Organic Chemistry, 40(23), 3444-3445 (1975)
The microwave spectrum, dipole moment, and structure of cyclopropyl carbinol.
Bhaumik A, et al.
Canadian Journal of Chemistry, 48(19) , 2949-2954 (1970)

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