481858
甲基对甲苯亚砜
97%
别名:
(±)-对甲苯甲基亚砜, (±)-甲基对甲苯亚砜, 1-甲基-4-(甲磺酰)苯, 1-甲烷亚磺酰基-4-甲基苯, 4-(甲基亚磺酰基)甲苯, 4-甲基苯基甲基亚砜, 4-甲苯甲基亚砜, 对甲基苯基甲基亚砜, 对甲苯甲基亚砜, 甲基4-甲基苯基亚砜
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关于此项目
线性分子式:
CH3C6H4S(O)CH3
化学文摘社编号:
分子量:
154.23
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
产品名称
甲基对甲苯亚砜, 97%
InChI
1S/C8H10OS/c1-7-3-5-8(6-4-7)10(2)9/h3-6H,1-2H3
SMILES string
Cc1ccc(cc1)S(C)=O
InChI key
FEVALTJSQBFLEU-UHFFFAOYSA-N
assay
97%
bp
113-114 °C/2 mmHg (lit.)
mp
44-46 °C (lit.)
functional group
sulfoxide
Quality Level
Application
对甲基苯甲酸亚砜可以用作通过醛与烯丙基三氯硅烷的烯丙基化来制备均烯丙基醇的催化剂。它可以用作氯钼络合物合成中的配体。
Disclaimer
低熔点固体
General description
甲基对甲苯基亚砜（MTSO）是烷基取代的对甲苯基亚砜，是一种路易斯碱。它作为四氯化硅的活化剂，用于氮杂 Diels-Alder 反应。
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
Addition compounds of MoO2Cl2 with chiral sulfoxides. First molecular structures of dioxomolybdenum complexes bearing chiral non-racemic sulfoxide as ligand.
Pedrosa MR, et al.
Inorgorganica Chimica Acta, 363(13), 3158-3164 (2010)
Luisa A Denkel et al.
PloS one, 6(11), e26974-e26974 (2011-11-11)
Production of reactive oxygen species represents a fundamental innate defense against microbes in a diversity of host organisms. Oxidative stress, amongst others, converts peptidyl and free methionine to a mixture of methionine-S- (Met-S-SO) and methionine-R-sulfoxides (Met-R-SO). To cope with such
A New Approach to Di-and Tetrasubstituted 2,3-Dihydropyridin-4(1H)-ones through Aza-Diels-Alder Reaction Promoted by Silicon Tetrachloride.
Peduto A, et al.
Synthesis, 4, 0643-0649 (2009)
Asymmetric allylation of aldehydes with allyltrichlorosilane promoted by chiral sulfoxides.
Massa A, et al.
Tetrahedron Letters, 44(38), 7179-7181 (2003)
Yuuka Masuyama et al.
Drug metabolism and pharmacokinetics, 35(3), 274-280 (2020-04-20)
Flavin containing monooxygenases (FMOs) represent one of the predominant types of phase I drug metabolizing enzymes (DMEs), and thus play an important role in the metabolism of xeno- and endobiotics for the generation of their corresponding oxides. These oxides often
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