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一般描述
Cyanogen bromide (CNBr) is a halogen halide. Its utility as a condensing agent during chemical ligation of oligodeoxyribonucleotides has been reported. Its threshold photoelectron (TPE) spectrum has been recorded under high resolution. The cryopolymerization of CNBr on irradiation has been investigated.
应用
与 C60P 5Cl 反应生成新型苯代异喹啉并[3′,4′:1,2][60]富勒烯。
Cyanogen bromide may be used:
- To activate polysaccharides for coupling with erythrocytes.
- As an oxidizing agent in the urine thaimine assay.
- In the preparation of 2-amino-5-(2′-thienyl)-1,3,4-oxadiazole.
警示用语：
Danger
危险分类
Acute Tox. 2 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Acute 1 - Eye Dam. 1 - Skin Corr. 1B
补充剂危害
储存分类代码
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGK
WGK 3
闪点(°F)
>149.0 °F - closed cup
闪点(°C)
> 65 °C - closed cup
个人防护装备
dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges, type P3 (EN 143) respirator cartridges
法规信息
新产品
Abdul-Sada, A.K. et al.
Chemical Communications (Cambridge, England), 307-307 (1998)
N I Sokolova et al.
FEBS letters, 232(1), 153-155 (1988-05-09)
Cyanogen bromide was found to condense oligodeoxyribonucleotides on a complementary template in aqueous solution. Optimum conditions for this vigorous and effective reaction were developed. CNBr proved to be useful for incorporation of phosphoramidate or pyrophosphate internucleotide bonds in DNA duplexes.
Threshold photoelectron spectroscopy of cyanogen bromide.
Yencha AJ, et al.
Chemical Physics Letters, 392(1), 202-208 (2004)
Coupling of polysaccharides to erythrocytes by cyanogen bromide.
A W Richter et al.
Scandinavian journal of immunology, 3(3), 365-368 (1974-01-01)
Oxadiazole: a biologically important heterocycle.
Somani RR and Shirodkar PY.
Der Pharma Chemica, 1(1), 130-140 (2009)
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