481378
烯丙基氯
别名:
3-氯-1-丙烯, 氯丙烯
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线性分子式:
CH2=CHCH2Cl
化学文摘社编号:
分子量:
76.52
UNSPSC Code:
12352100
NACRES:
NA.21
PubChem Substance ID:
EC Number:
203-457-6
Beilstein/REAXYS Number:
635704
MDL number:
InChI key
OSDWBNJEKMUWAV-UHFFFAOYSA-N
InChI
1S/C3H5Cl/c1-2-3-4/h2H,1,3H2
SMILES string
ClCC=C
vapor density
2.6 (vs air)
vapor pressure
20.58 psi ( 55 °C), 5.71 psi ( 20 °C)
assay
98.0% (returnable containers)
expl. lim.
11.2 %
refractive index
n20/D 1.414 (lit.)
bp
44-46 °C (lit.)
mp
−130 °C (lit.)
density
0.939 g/mL at 25 °C (lit.)
storage temp.
2-8°C
Quality Level
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Packaging
signalword
Danger
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - Muta. 2 - Skin Irrit. 2 - STOT RE 2 - STOT SE 3
target_organs
Nervous system,Liver,Kidney, Respiratory system
存储类别
3 - Flammable liquids
wgk
WGK 2
flash_point_f
-25.6 °F
flash_point_c
-32 °C
ppe
Eyeshields, Faceshields, Gloves
法规信息
新产品
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Heike Burghart-Stoll et al.
Organic letters, 13(10), 2730-2733 (2011-04-30)
A (DHQN)(2)AQN-promoted asymmetric dihydroxylation (92% ee) of the allyl chloride derived from enynol (E)-13 and an 8-step sequence provided access to the hydroxyethylated furanone (R)-21. Oxidation with MnO(2) furnished 50% furanone (+)-(R)-2a and 2.7% isomeric furanone (+)-(R)-3a. (R)-2a possesses the
Vikas Sikervar et al.
The Journal of organic chemistry, 77(11), 5132-5138 (2012-04-27)
A coupling strategy for the synthesis of 2,4-dimethyl-1α,25(OH)(2)D(3) is achieved which involves methylation of a pro-A ring vinyl sulfone and in situ traping of the allyl sulfonyl anion with a CD ring allyl chloride. TBAF-promoted 1,2-eliminative desulfonylation and concomitant silyl
Carbocycle synthesis through facile and efficient palladium-catalyzed allylative de-aromatization of naphthalene and phenanthrene allyl chlorides.
Shirong Lu et al.
Angewandte Chemie (International ed. in English), 47(23), 4366-4369 (2008-04-30)
Kai Abersfelder et al.
Journal of the American Chemical Society, 130(12), 4114-4121 (2008-03-04)
The rearrangements of (chlorosilyl)disilenes R2(Cl)Si-(Tip)Si=SiTip2 (5a,b: Tip = 2,4,6-iPr3C6H2, a: R = Me, b: R = Ph) quantitatively yield the isomeric chlorocyclotrisilanes (6a,b). The disilene precursors 5a,b are, in turn, accessible from the reactions of the disilenide Tip2Si=Si(Tip)Li (1), that
B M de Rooij et al.
Drug metabolism and disposition: the biological fate of chemicals, 24(7), 765-772 (1996-07-01)
Allyl chloride (AC) is used as intermediate in the synthesis of epichlorohydrin (ECH). We investigated the biotransformation of AC in rats to select potential urinary biomarkers of exposure. For this purpose, we developed analytical methods to measure different selected urinary
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