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Merck
CN
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文件

480835

Sigma-Aldrich

2-溴-4-甲基苯甲醚

97%

别名:

3-溴-4-甲氧基甲苯

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About This Item

线性分子式:
Br(CH3)C6H3OCH3
CAS号:
22002-45-5
分子量:
201.06
EC 号:
244-705-3
MDL编号:
MFCD00017783
UNSPSC代码:
12352100
PubChem化学物质编号:
24871722
NACRES:
NA.22

质量水平

100

检测方案

97%

折射率

n20/D 1.565 (lit.)

bp

124-125 °C/20 mmHg (lit.)

mp

15.5 °C (lit.)

密度

1.392 g/mL at 25 °C (lit.)

SMILES字符串

COc1ccc(C)cc1Br

InChI

1S/C8H9BrO/c1-6-3-4-8(10-2)7(9)5-6/h3-5H,1-2H3

InChI key

DHPUIKWBNXTXOB-UHFFFAOYSA-N

相关类别

一般描述

2-Bromo-4-methylanisole can be prepared via bromination of 4-methylanisole using poly(4-vinylpyridinium bromochromate).

应用

2-Bromo-4-methylanisole may be used in the synthesis of:
  • 1,6-bis(2-hydroxy-5-methylphenyl)pyridine (H2mdppy)
  • 1,8-dimethoxy-4-methylanthra-quinone
  • ethyl 2-(2-methoxy-5-methylphenyl)-2-methyl-4-oxocyclopentanecarboxylate
It may be used as starting material in the multi-step synthesis of sesquiterpene (±)-herbertenolide.

象形图

Exclamation mark
GHS07

警示用语：

Warning

危险声明

H315,H319,H335

危险分类

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

WGK

WGK 3

闪点(°F)

235.4 °F

闪点(°C)

113 °C

个人防护装备

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

分析证书(COA)

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Highly efficient white organic electroluminescence from a double-layer device based on a boron hydroxyphenylpyridine complex.
Liu Y, et al.
Angewandte Chemie (International Edition in English), 41(1), 182-184 (2002)
Total synthesis of (?)-herbertenolide by stereospecific formation of vicinal quaternary centers in a crystalline ketone.
Ng D, et al.
Organic Letters, 6(4), 645-647 (2004)
Poly (4-vinylpyridinium bromochromate): an efficient reagent for bromination of aromatic compounds.
Albadi J, et al.
Monatshefte fur Chemie / Chemical Monthly, 144(2), 179-181 (2013)
Unambiguous synthesis and spectral characterization of 1,8-dihydroxy-4-methylanthraquinone.
Wang A, et al.
ARKIVOC (Gainesville, FL, United States), 1, 80-84 (2002)
Lipase-Promoted Access to Phenolic Herbertane-Type Sesquiterpenes: (+)-1, 14-Herbertenediol, (-)-a-Herbertenol, (-)-Herbertenediol and Their Enantiomers.
Acherar S, et al.
European Journal of Organic Chemistry, 2004(24), 5092-5099 (2004)

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