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安全信息

480495

Sigma-Aldrich

1,3-双(4-甲氧基苯基)-1,3-丙二酮

97%

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About This Item

线性分子式:
(CH3OC6H4CO)2CH2
CAS号:
18362-51-1
分子量:
284.31
EC 号:
242-233-2
MDL编号:
MFCD00025817
UNSPSC代码:
12352100
PubChem化学物质编号:
24871687

方案

97%

mp

108-115 °C (lit.)

SMILES字符串

COc1ccc(cc1)C(=O)CC(=O)c2ccc(OC)cc2

InChI

1S/C17H16O4/c1-20-14-7-3-12(4-8-14)16(18)11-17(19)13-5-9-15(21-2)10-6-13/h3-10H,11H2,1-2H3

InChI key

GNMDORSUZRRMFS-UHFFFAOYSA-N

一般描述

1,3-Bis(4-methoxyphenyl)-1,3-propanedione is a diketone. It is formed as an intermediate during the synthesis of bisphenols.

应用

1,3-Bis(4-methoxyphenyl)-1,3-propanedione (Hpmdbm) may be used:
  • As a reactant in the preparation of 1,3-bis(4-hydroxyphenyl)-1,3-propanedione.
  • As a starting material in the synthesis of propylpyrazole triol (PPT).
  • As a ligand in the synthesis of [NaFe6(OCH3)12(pmdbm)6]ClO4, an iron(III)-oxo cluster.

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Gloves, type N95 (US)

法规信息

新产品

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
43896DJV
43896DJ
18012PO
12325MO
10312LR

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James J Devery et al.
Synlett : accounts and rapid communications in synthetic organic chemistry, (9)(9), 1490-1494 (2009-01-01)
A convenient approach for the synthesis of tetrasubstituted pyrazoles is described. The method involves the treatment of 1,3-diketones and allyltrimethylsilane with CAN followed by cerium-catalyzed addition of substituted hydrazines to construct pyrazoles in good yields.
Thermostable and heat resistant aromatic polyethers based on heterocyclic bisphenols.
Rusanov AL and Belomoina NM.
Polymer Science, Series C, 51(1), 87-125 (2009)
Single-Ion versus Dipolar Origin of the Magnetic Anisotropy in Iron (III)-Oxo Clusters: A Case Study.
Abbati GL, et al.
Chemistry (Weinheim An Der Bergstrasse, Germany), 7(8), 1796-1807 (2001)
β-Diketone reagents for the determination of borate in water.
Lambert JL, et al.
Analytical Chemistry, 50(6), 820-822 (1978)

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