质量水平
检测方案
99%
bp
183 °C/20 mmHg (lit.)
mp
47-49 °C (lit.)
SMILES字符串
OC(C#C)(c1ccccc1)c2ccccc2
InChI
1S/C15H12O/c1-2-15(16,13-9-5-3-6-10-13)14-11-7-4-8-12-14/h1,3-12,16H
InChI key
SMCLTAARQYTXLW-UHFFFAOYSA-N
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一般描述
1,1-Diphenyl-2-propyn-1-ol is an alkynol.
应用
1,1-Diphenyl-2-propyn-1-ol may be used in the synthesis of:
- (PCy3)2Cl2Ru(3-phenylinden-1-ylidene) (Cy=cyclohexyl)
- thieno-2H-chromenes
- {Ru(Cp*)(CO)[=C(OMe)CH=CPh2][Ph2PCH2C(=O)tBu]}[PF6] (Cp=cyclopentadienyl)
警示用语:
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
WGK
WGK 3
闪点(°F)
235.4 °F
闪点(°C)
113 °C
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
Cross Metathesis Allowing the Conversion of a Ruthenium Indenylidene Complex into Grubbs' Catalyst.
Advanced Synthesis & Catalysis, 346(8), 917-920 (2004)
Synthesis and Reactivity of [Ru(Cp*)(L)(MeCN)2][PF6](L= Ph2POMe or Ph2P-o-tolyl) and {Ru(Cp*)[Ph2PCH2C(tBu)=O](MeCN)}[PF6] Complexes, Their Involvement as Catalyst Precursors..?
European Journal of Inorganic Chemistry, 2006(7), 1371-1380 (2006)
Synthesis of photochromic thieno-2H-chromene derivatives.
Dyes and Pigments, 47(3), 219-229 (2000)
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 233, 118191-118191 (2020-03-07)
A well-designed naphthopyran-diaminomaleonitrile dyad (sensor 1) has been synthesized successfully, its molecular structure was well characterized by NMR and mass spectrometry. Sensor 1 exhibits excellent photochromic and photochromic fluorescence switch performance with reversible color change and good fatigue resistance upon
Nature communications, 9(1), 2634-2634 (2018-07-08)
Ensemble control has been intensively pursued for decades to identify sustainable alternatives to the Lindlar catalyst (PdPb/CaCO3) applied for the partial hydrogenation of alkynes in industrial organic synthesis. Although the geometric and electronic requirements are known, a literature survey illustrates
商品
Alkynes' versatility enables reactions like addition, metathesis, hydroboration, cleavage, coupling, and cycloadditions in synthetic chemistry.
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