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Merck
CN

47695

Sigma-Aldrich

芴甲氧羰基-S-三苯甲基-L-半胱氨酸

≥95.0% (sum of enantiomers, HPLC)

别名:

N-(9-芴甲氧羰基)-S-三苯甲基-L-半胱氨酸, Nα-Fmoc-S-三苯甲基-L-半胱氨酸

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About This Item

经验公式(希尔记法):
C37H31NO4S
分子量:
585.71
Beilstein:
4221286
MDL编号:
UNSPSC代码:
12352209
eCl@ss:
32160406
PubChem化学物质编号:
NACRES:
NA.26

质量水平

方案

≥95.0% (sum of enantiomers, HPLC)

旋光性

[α]20/D +16.0±2°, c = 1% in THF

反应适用性

reaction type: Fmoc solid-phase peptide synthesis

mp

170-173 °C (lit.)

应用

peptide synthesis

官能团

Fmoc

储存温度

2-8°C

SMILES字符串

OC(=O)[C@H](CSC(c1ccccc1)(c2ccccc2)c3ccccc3)NC(=O)OCC4c5ccccc5-c6ccccc46

InChI

1S/C37H31NO4S/c39-35(40)34(38-36(41)42-24-33-31-22-12-10-20-29(31)30-21-11-13-23-32(30)33)25-43-37(26-14-4-1-5-15-26,27-16-6-2-7-17-27)28-18-8-3-9-19-28/h1-23,33-34H,24-25H2,(H,38,41)(H,39,40)/t34-/m0/s1

InChI key

KLBPUVPNPAJWHZ-UMSFTDKQSA-N

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一般描述

Fmoc-Cys(Trt)-OH是Fmoc固相肽合成中常用的氨基酸。

应用

Fmoc-Cys(Trt)-OH是一种N末端保护的半胱氨酸衍生物,可用于肽合成。一些例子包括:
  • 合成单官能和双官能化铂(IV)络合物以靶向血管生成肿瘤脉管系统。
  • 通过固相合成将肽酰肼作为硫酯替代物进行天然化学连接来合成蛋白质。
  • 通过将还原糖与肽的半胱氨酸残基缀合来合成糖结合物。

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Gloves, type N95 (US)


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Nature Protocols, 8(12), 2483-2483 (2013)
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