472565
氰基膦酸二乙酯
90%
别名:
DEPC, 氰代磷酸二乙酯
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线性分子式:
(CH3CH2O)2P(O)CN
化学文摘社编号:
分子量:
163.11
EC Number:
220-936-5
UNSPSC Code:
12352100
PubChem Substance ID:
Beilstein/REAXYS Number:
1768938
MDL number:
Assay:
90%
InChI key
ZWWWLCMDTZFSOO-UHFFFAOYSA-N
InChI
1S/C5H10NO3P/c1-3-8-10(7,5-6)9-4-2/h3-4H2,1-2H3
SMILES string
CCOP(=O)(OCC)C#N
assay
90%
refractive index
n20/D 1.403 (lit.)
bp
104-105 °C/19 mmHg (lit.)
density
1.075 g/mL at 25 °C (lit.)
storage temp.
2-8°C
General description
氰基膦酸二乙酯（DCNP，一种塔崩模拟物， DECP）是一种神经毒剂模拟物。使用荧光素（一种可逆荧光传感剂）对其进行检测已有报道。 它在合适的有机催化剂（不同的胺、氨基醇和二醇）存在下的降解已有研究。
Application
肽合成的偶联剂。苯酚的磷酸化试剂。羧酸荧光衍生化的活化剂，可通过 HPLC 分离活化剂。
Other Notes
含磷酸三乙酯
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 2 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Eye Dam. 1 - Skin Corr. 1B
supp_hazards
存储类别
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
wgk
WGK 3
flash_point_f
176.0 °F - closed cup
flash_point_c
80 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
新产品
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Farkhondeh Fathi et al.
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A simple electrochemical method has been proposed for the preparation of silver nanoparticles that can be used for the detection of cyanide. Both the electrochemical behavior and morphology of the Ag nanoparticles have been characterized in the presence of KCN
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T C Bruice et al.
Proceedings of the National Academy of Sciences of the United States of America, 89(5), 1700-1704 (1992-03-01)
The structures of the compounds we call 3a, 3b, and 3c-compounds that incorporate (i) the tripyrrole peptide of the minor-groove-binding distamycin class of compounds and (ii) polyamine ligands that extend from the minor groove and can interact with phosphodiester bonds--were
T Toyo'oka et al.
Journal of chromatography, 588(1-2), 61-71 (1991-12-27)
Four new 2,1,3-benzoxadiazole amine reagents having different functional groups at the 4- and 7-positions, [4-nitro-7-N-piperazino-2,1,3-benzoxadiazole (NBD-PZ), 4-(N,N-dimethylaminosulphonyl)-7-N-piperazino-2,1,3-benzoxad iazole (DBD-PZ), 4-(N,N-dimethylaminosulphonyl)-7-N-cadaverino-2,1,3-benzoxad iazole (DBD-CD) and ammonium 7-N-piperazino-2,1,3-benzoxadiazole-4-sulphonate (SBD-PZ)] were synthesized as fluorogenic tagging reagents for carboxylic acids in high-performance liquid chromatography. The
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