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Merck
CN

471259

甲基磺酰氯

≥99.7%

别名:

甲基磺酰氯, 甲磺酰氯

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关于此项目

线性分子式:
CH3SO2Cl
化学文摘社编号:
分子量:
114.55
UNSPSC Code:
12352101
NACRES:
NA.22
PubChem Substance ID:
EC Number:
204-706-1
Beilstein/REAXYS Number:
506297
MDL number:
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产品名称

甲基磺酰氯, ≥99.7%

InChI key

QARBMVPHQWIHKH-UHFFFAOYSA-N

InChI

1S/CH3ClO2S/c1-5(2,3)4/h1H3

SMILES string

CS(Cl)(=O)=O

assay

≥99.7%

refractive index

n20/D 1.452 (lit.)

bp

60 °C/21 mmHg (lit.)

density

1.48 g/mL at 25 °C (lit.)

storage temp.

2-8°C

Quality Level

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Application

甲磺酰氯可用于伯醇的甲磺酸化,以合成相应的甲磺酸盐。它也可以用于将胺转化为相应的磺酰胺。

pictograms

Skull and crossbonesCorrosion

signalword

Danger

Hazard Classifications

Acute Tox. 1 Inhalation - Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1B - Skin Sens. 1 - STOT SE 3

target_organs

Respiratory system

存储类别

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 2

flash_point_f

215.6 °F - closed cup

flash_point_c

102 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

法规信息

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Methanesulfonyl Chloride.
Vaillancourt V
e-EROS Encyclopedia of Reagents for Organic Synthesis. (2007)
Base-free monosulfonylation of amines using tosyl or mesyl chloride in water
Kamal A
Tetrahedron Letters, 49(2), 348-353 (2008)
Water-solvent method for tosylation and mesylation of primary alcohols promoted by KOH and catalytic amines.
Morita J I
Green Chemistry, 7(10), 711-715 (2005)
Shengzhuang Tang et al.
The Journal of organic chemistry, 85(5), 2945-2955 (2020-02-06)
Despite its importance in the design of photocaged molecules, less attention is focused on linker chemistry than the cage itself. Here, we describe unique uncaging properties displayed by two coumarin-caged thymidine compounds, each conjugated with (2) or without (1) an
Jan-Hendrik Kruse et al.
Macromolecular rapid communications, 40(10), e1800857-e1800857 (2019-01-18)
Polydehydroalanine (PDha) is a polyampholyte featuring both a -NH2 and a -COOH in every repeat unit and with that presents a rather high charge density. The synthesis and polymerization of two monomers, benzyl 2-tert-butoxycarbonylaminoacrylate and methyl 2-benzyloxycarbonylaminoacrylate is herein reported

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