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蒸汽密度
4.46 (vs air)
质量水平
蒸汽压
1.9 mmHg ( 20 °C)
检测方案
≥99.5%
形式
liquid
自燃温度
594 °F
expl. lim.
10 %
折射率
n20/D 1.417 (lit.)
pH值(酸碱度)
11.1 (20 °C, 1 g/L)
bp
159 °C (lit.)
mp
−62 °C (lit.)
溶解性
water: soluble 3.8 g/L at 20 °C
密度
0.767 g/mL at 25 °C (lit.)
SMILES字符串
CCCCNCCCC
InChI
1S/C8H19N/c1-3-5-7-9-8-6-4-2/h9H,3-8H2,1-2H3
InChI key
JQVDAXLFBXTEQA-UHFFFAOYSA-N
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一般描述
二丁胺是一种高活性的催化剂,通常用作异氰酸酯衍生化反应中的试剂。
应用
二丁胺可用作反应物以合成:通过与芳基氯化物和溴化物的 Pd 催化 Buchwald-Hartwig 胺化反应合成
也可用作:
- N, N
- -二丁基-4-甲基苯胺。
- 通过与乙酸异丙烯酯的乙酰化反应合成 N,N-二丁基二乙酰胺。
也可用作:
- 不同消除反应中的强阻碍碱。
- 有机催化剂,通过芳香族醛、丙二腈和巴比妥酸的多组分缩合反应合成环状吡喃 [2,3-d] 嘧啶衍生物。
警示用语:
Danger
危险分类
Acute Tox. 2 Inhalation - Acute Tox. 3 Dermal - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1A
WGK
WGK 1
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
Chemistry of blocked isocyanates. II. Kinetics and mechanism of the reaction of dibutylamine with phenyl and 2-methylphenyl oxime carbamates.
The Journal of Organic Chemistry, 37(15), 2455-2460 (1972)
Determination of complex mixtures of airborne isocyanates and amines. Part 3. Methylenediphenyl diisocyanate, methylenediphenylamino isocyanate and methylenediphenyldiamine and structural analogues after thermal degradation of polyurethane
Analyst, 122, 275-278 (1997)
Determination of complex mixtures of airborne isocyanates and amines. Part 1. Liquid chromatography with ultraviolet detection of monomeric and polymeric isocyanates as their dibutylamine derivatives.
Analyst, 121(8), 1095-1099 (1996)
Dibutylamine (DBA): A highly efficient catalyst for the synthesis of pyrano [2, 3-d] pyrimidine derivatives in aqueous media
Journal of Taibah University for Science , 10, 9-18 (2016)
New Insight on the Study of the Kinetic of Biobased Polyurethanes Synthesis Based on Oleo-Chemistry.
Molecules (Basel, Switzerland), 24(23) (2019-12-01)
Nowadays, polyols are basic chemicals for the synthesis of a large range of polymers, such as polyurethane foams (PUF), which are produced with several other compounds, such as polyisocyanates. During the last decades, the oleo-chemistry has developed several routes from
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