推荐产品
方案
97%
mp
78-82 °C (lit.)
SMILES字符串
[O-][N+](=O)c1ccccc1Sc2ccccc2
InChI
1S/C12H9NO2S/c14-13(15)11-8-4-5-9-12(11)16-10-6-2-1-3-7-10/h1-9H
InChI key
ZPWNCSAEXUDWTN-UHFFFAOYSA-N
一般描述
2-Nitrophenyl phenyl sulfide is an aromatic sulfide bearing a nitro group. It has been reported to undergo sulfur oxidation on electrospray ionization in the positive-ion mode. Accurate masses of fragment ions generated by electrospray ionization (ESI) - collisionally activated dissociation (CAD) of [M + H]+ ions of 2-nitrophenyl phenyl sulfide have been evaluated.
警示用语:
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
法规信息
新产品
Joseph T Moolayil et al.
International journal of mass spectrometry, 283(1-3), 222-228 (2010-02-18)
Aromatic sulfides bearing a nitro group undergo sulfur oxidation upon electrospray ionization in the positive-ion mode. For example, 2-nitrophenyl phenyl sulfide, its para nitro isomer, and its chloro and methyl substituted analogs pick up an oxygen atom to afford [M
Joseph T Moolayil et al.
Journal of the American Society for Mass Spectrometry, 18(12), 2204-2217 (2007-11-03)
A novel gas-phase electrophilic cyclization, initiated by the protonation of a nitro group, occurs for 2-nitrophenyl phenyl ether and for the analogous sulfide and amine, leading to heterocyclic intermediates in each case. Subsequently, the cyclic intermediates dissociate via two pathways:
Photochemical Rearrangement of 2-Nitrophenyl Phenyl Sulfoxide to 2-Nitrosophenyl Phenyl Sulfone.
Tanikaga R and Kaji A.
Bulletin of the Chemical Society of Japan, 46(12), 3814-3817 (1973)
Ellen K Parker et al.
Analytical and bioanalytical chemistry, 411(21), 5405-5413 (2018-11-02)
Preterm birth (PTB) is defined as birth before the 37th week of pregnancy and results in 15 million early deliveries worldwide every year. Presently, there is no clinical test to determine PTB risk; however, a panel of nine biomarkers found
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