所有图片(1)
别名:
2,N-Dimethylaniline, 2-Methyl-N-methylaniline, N,2-Dimethylaniline, N,2-Dimethylbenzenamine, N,o-Dimethylaniline, N-(2-Methylphenyl)methylamine, N-Methyl-2-methylaniline, N-Methyl-2-methylbenzenamine, N-Methyl-N-(o-tolyl)amine, N-Methyl-o-methylaniline, o,N-Dimethylaniline, Methyl(o-tolyl)amine, NSC 9395
线性分子式:
CH3C6H4NHCH3
CAS号:
分子量:
121.18
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
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检测方案
≥95%
bp
177-204 °C/740 mmHg (lit.)
密度
0.981 g/mL at 25 °C (lit.)
SMILES字符串
CNc1ccccc1C
InChI
1S/C8H11N/c1-7-5-3-4-6-8(7)9-2/h3-6,9H,1-2H3
InChI key
GUAWMXYQZKVRCW-UHFFFAOYSA-N
一般描述
N-Methyl-o-toluidine can be synthesized by reacting o-toluidine and benzotriazole.
应用
N-Methyl-o-toluidine may be used in the preparation of 2-substituted N-methylindoles.
Reactant for:
- Palladium-catalyzed coupling reactions
- Palladium-catalyzed amination of bromoindazoles
警示用语：
Danger
危险分类
Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Chronic 3 - STOT RE 2
WGK
WGK 3
闪点(°F)
closed cup
闪点(°C)
closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Jaakko Laakia et al.
Talanta, 132, 889-893 (2014-12-06)
Eight selected isomeric amines were ionized using atmospheric pressure chemical ionization and atmospheric pressure photoionization producing a protonated molecule [M+H](+) for each amine. The mobility of these ions was measured by ion mobility spectrometry. The amine compound class was shown
A Practical Synthetic Method for N-Methyl-o-Toluidine.
Katritzky AR and Akutagawa K.
Organic preparations and procedures international, 21(3), 340-341 (1989)
Carbon dioxide: a reagent for the simultaneous protection of nucleophilic centers and the activation of alternative locations to electrophilic attack. XVI, A novel synthetic method for the side-chain functionalization of N-methyl-o-toluidine and for the preparation of 2-substituted N-methylindoles.
Katritzky AR, et al.
Heterocycles, 30(1), 407-414 (1990)
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