466212
1,1,2-三氯乙烷
contains ≤3% 2-propanol as stabilizer, 97%
别名:
β-三氯乙烷, 三氯化乙烯
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关于此项目
线性分子式:
ClCH2CHCl2
化学文摘社编号:
分子量:
133.40
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
1731726
产品名称
1,1,2-三氯乙烷, contains ≤3% 2-propanol as stabilizer, 97%
InChI
1S/C2H3Cl3/c3-1-2(4)5/h2H,1H2
SMILES string
ClCC(Cl)Cl
InChI key
UBOXGVDOUJQMTN-UHFFFAOYSA-N
assay
97%
contains
≤3% 2-propanol as stabilizer
refractive index
n20/D 1.471 (lit.)
bp
110-115 °C (lit.)
density
1.435 g/mL at 25 °C (lit.)
functional group
chloro
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Application
- 先进材料开发：UiO-66 3D光子晶体合成研究的重点在于高效蒸汽检测（efficient vapor detection）用新材料的制备，为传感器技术的进步提供支持 （Wang et al., 2022）。
General description
1,1,2-三氯乙烷（1,1,2-TCA）是一种氯化的脂肪烃，是一种常见的地下水污染物。 1,1,2-TCA的微生物排毒作用已有研究。 据报道，Ni被负载在介孔二氧化硅（SBA-16）上可催化1,1,2-三氯乙烷的加氢脱氯反应。 气态和液态1,1,2-三氯乙烷的旋转异构体已通过红外吸收光谱进行了研究。
signalword
Danger
Hazard Classifications
Acute Tox. 3 Inhalation - Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Aquatic Chronic 3 - Carc. 2
supp_hazards
存储类别
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
法规信息
危险化学品
此项目有
Infrared Absorption Investigation on the Rotational Isomerism of 1, 1, 2-Trichloroethane.
Kuratani K and Mizushima S-I.
J. Chem. Phys. , 22(8), 1403-1405 (1954)
Single-step preparation of Ni catalysts supported on mesoporous silicas (SBA-15 and SBA-16) and the effect of pore structure on the selective hydrodechlorination of 1, 1, 2-trichloroethane to VCM.
Park Y, et al.
Catalysis Today, 97(2), 195-203 (2004)
Siyan Zhao et al.
PloS one, 10(3), e0119507-e0119507 (2015-04-04)
1,1,2-trichloroethane (1,1,2-TCA) has become a common groundwater pollutant due to historically extensive utilization, improper disposal, as well as from incomplete dechlorination of 1,1,2,2-tetrachloroethane. Currently, limited information is available on microbial detoxification of 1,1,2-TCA. Desulfitobacterium sp. strain PR, which was isolated
Chuanjie Cheng et al.
The Journal of organic chemistry, 74(15), 5671-5674 (2009-06-19)
In the presence of 1,1,2-trichloroethane, a novel procedure for the Pd-C catalytic N-debenzylation of benzylamines was established. The method proceeded in a synergistic catalytic system and directly gave the products as crystal amine hydrochlorides in practically quantitative yields.
Robert Zaleśny et al.
Journal of molecular modeling, 13(6-7), 785-791 (2007-04-18)
The UV-Vis spectra of series of polymethylmethacrylate (PMMA) copolymers with attached trans-azobenzene derivatives were measured in 1,1,2-trichloroethane. In order to gain some insight into the recorded spectra, the quantum chemical calculations were performed for the substituted azobenzenes using both configuration
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