464651
钯
powder, <75 μm, 99.9% trace metals basis
别名:
Palladium (nanoparticles), Palladium (powder), Palladium black, Palladium element
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关于此项目
线性分子式:
Pd
化学文摘社编号:
分子量:
106.42
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12141733
EC Number:
231-115-6
MDL number:
Application
- Laccases as palladium oxidases: This study introduces a coupled catalytic system involving an enzyme and a palladium(II) catalyst for the aerobic oxidation of alcohol, showcasing a novel application of palladium in green chemistry (Y Mekmouche et al., 2015).
- Palladium-based nanomaterials: synthesis and electrochemical applications: Reviews the synthesis and utility of palladium-based nanomaterials, with a focus on their electrochemical applications, particularly in energy conversion and storage (A Chen, C Ostrom, 2015).
- Strategies for sustainable palladium catalysis: Discusses the sustainability of palladium catalysis, including methods to recycle and reuse palladium and strategies to reduce the environmental impact of palladium sourcing (S McCarthy et al., 2021).
signalword
Danger
hcodes
Hazard Classifications
Eye Irrit. 2 - Flam. Sol. 1 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
4.1B - Flammable solid hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type P3 (EN 143) respirator cartridges
法规信息
新产品
此项目有
Xuxing Chen et al.
Organic & biomolecular chemistry, 11(16), 2582-2585 (2013-03-19)
A one-pot two-step synthesis of versatile indenones has been developed. This palladium(II)-catalyzed transformation involves generation and condensation of ortho-functionalized 1,2-benzils from 2-(2-arylethynylphenyl)acetonitriles using Ph2SO as the oxidant. The resulting 3-cyanoindenones can be converted to various valuable molecules.
Stefano Nicolai et al.
The Journal of organic chemistry, 78(8), 3783-3801 (2013-03-21)
Tetrahydrofurans and pyrrolidines are among the most important heterocycles found in bioactive compounds. Cyclization-functionalization domino reactions of alcohols or amines onto olefins constitute one of the most efficient methods to access them. In this context, oxy- and aminoalkynylation are especially
Meng Wang et al.
Organic & biomolecular chemistry, 11(16), 2574-2577 (2013-03-15)
A novel Pd/Cu catalyzed domino reaction for the synthesis of functionalized pyrrolo[1,2-b]pyridazines from readily accessible (hetero)aryl propargyl alcohols and 1-amino-2-bromopyrroles was developed. This cascade process involves a Sonogashira cross-coupling reaction, an isomerization and an intramolecular condensation.
Kathrin Ulbrich et al.
The Journal of organic chemistry, 78(8), 4202-4206 (2013-04-03)
Racemic 4-hydroxycyclopentenone, readily derived from furfuryl alcohol, can be transformed via its O-Boc derivative to 4-acyloxy, 4-aryloxy-, 4-amino-, or 4-thio-substituted cyclopentenones with high enantioselectivity by palladium-catalyzed kinetic resolution via nucleophilic allylic substitutions. Applying this methodology, a short formal synthesis of
Z Y Bian et al.
Water science and technology : a journal of the International Association on Water Pollution Research, 67(8), 1873-1879 (2013-04-13)
A Pd/C gas-diffusion cathode which generated H2O2 through a two-electron reduction process of fed oxygen molecule was used to degrade 4-chlorophenol in an undivided electrolysis device. The kinetics of 4-chlorophenol degradation has been investigated by the electrochemical oxidation processes. By
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