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Merck
CN

463922

Sigma-Aldrich

偏钨酸铵 水合物

99.99% trace metals basis

别名:

Ammonium tungsten oxide hydrate, Hexaammonium wolframate hydrate

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About This Item

线性分子式:
(NH4)6H2W12O40 · xH2O
CAS号:
分子量:
2956.30 (anhydrous basis)
EC 号:
MDL编号:
UNSPSC代码:
12352302
PubChem化学物质编号:
NACRES:
NA.23

质量水平

检测方案

99.99% trace metals basis

形式

powder

反应适用性

reagent type: catalyst
core: tungsten

杂质

≤150.0 ppm Trace Metal Analysis

mp

100 °C (dec.) (lit.)

SMILES字符串

N.N.N.N.N.N.O.O[W]1O[W](O)(=O)(O1)O[W]2(=O)(=O)O[W](O)(=O)(O2)O[W]3(=O)(=O)O[W](O)(=O)(O3)O[W]4(=O)(=O)O[W](O)(=O)(O[W]5(=O)(=O)O[W](O)(=O)(O[W]6(=O)(=O)O[W](O)(O)O6)O5)O4

InChI

1S/6H3N.9H2O.32O.12W/h6*1H3;9*1H2;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;/q;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;6*+1;+2/p-8

InChI key

ZBHPUDGBNLMJQH-UHFFFAOYSA-F

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一般描述

偏钨酸铵是一种 Keggin 型杂多矿化合物。它可以通过钨酸铵溶液的缩聚来制备。它被广泛用作制备加氢裂化钨催化剂的前体,以及燃料电池催化剂。

应用

偏钨酸铵可用作合成以下物质的前体:
  • 用于纤维素氢解的碳负载钨催化剂。
  • 正构烷烃双官能团加氢异构化的还原钨和混合氧化钨催化剂。
  • 通过化学气相沉积方法合成混合 2D/3D 二硒化钨晶体管。

象形图

CorrosionExclamation mark

警示用语:

Danger

危险声明

预防措施声明

危险分类

Acute Tox. 4 Oral - Eye Dam. 1

WGK

WGK 2

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves


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Gwang Hwi An et al.
Small (Weinheim an der Bergstrasse, Germany), 16(43), e2003326-e2003326 (2020-10-01)
While a hexagonal WS2 monolayer, grown by chemical vapor deposition, exhibits distinctive patterns in photoluminescence mapping, segmented with alternating S-vacancy (SV) and W-vacancy (WV) domains in a single crystal, the formation mechanism for native alternating defect domains remains unresolved to
Hanyu Zhang et al.
Nanoscale, 12(15), 8344-8354 (2020-04-03)
By understanding how the environmental composition impacts the optoelectronic properties of transition metal dichalcogenide monolayers, we demonstrate that simple photoluminescence (PL) measurements of tungsten disulfide (WS2) monolayers can differentiate relative humidity environments. In this paper, we examine the PL and
Jung Ho Kim et al.
Scientific reports, 9(1), 9164-9164 (2019-06-27)
Nanophotonic devices manipulating light for high-speed computing are a counterpart of speed-limited electronic circuits. Although plasmonic circuits are a promising platform for subwavelength miniaturization, the logic-operation principle is still limited to mimicking those of photonic waveguides using phase shifts, polarization
Ze-Da Meng et al.
Nanoscale research letters, 6(1), 459-459 (2011-07-22)
WO3-treated fullerene/TiO2 composites (WO3-fullerene/TiO2) were prepared using a sol-gel method. The composite obtained was characterized by BET surface area measurements, X-ray diffraction, scanning electron microscopy, energy dispersive X-ray analysis, transmission electron microscopy, and UV-vis analysis. A methyl orange (MO) solution
Xiao Zhang et al.
Science advances, 6(40) (2020-10-02)
The direct growth of single-walled carbon nanotubes (SWCNTs) with narrow chiral distribution remains elusive despite substantial benefits in properties and applications. Nanoparticle catalysts are vital for SWCNT and more generally nanomaterial synthesis, but understanding their effect is limited. Solid catalysts

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