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463779

Sigma-Aldrich

氯化钌 (III) 水合物

99.98% trace metals basis

别名:

三氯化钌

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About This Item

线性分子式:
RuCl3 · xH2O
CAS号:
14898-67-0
分子量:
207.43 (anhydrous basis)
EC 号:
233-167-5
MDL编号:
MFCD00149844
UNSPSC代码:
12352302
PubChem化学物质编号:
24870096
NACRES:
NA.23
方案:
99.98% trace metals basis
表单:
powder and chunks

质量水平

100

方案

99.98% trace metals basis

表单

powder and chunks

反应适用性

reagent type: catalyst
core: ruthenium

杂质

≤250.0 ppm Trace Metal Analysis

SMILES字符串

O.Cl[Ru](Cl)Cl

InChI

1S/3ClH.H2O.Ru/h3*1H;1H2;/q;;;;+3/p-3

InChI key

BIXNGBXQRRXPLM-UHFFFAOYSA-K

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相关类别

一般描述

氯化钌（III）水合物具有优异的催化活性，这是因为钌的氧化还原性质适用于燃料电池和其它电化学设备。 它能够促进电荷转移并具有光敏行为。

应用

氯化钌（III）水合物可用于：
  • 作为制备超低钌负载石墨烯气凝胶的前体，该气凝胶在析氢反应（HER）、析氧反应（OER）和氧还原反应（ORR）中表现出电催化性能。
  • 作为掺杂剂，通过旋涂技术制备用于介观钙钛矿太阳能电池的掺钌TiO22 电子传输层。这有助于提高光转换效率和空气稳定性。
  • 通过小分子自组装热解法制备超均匀钌纳米簇催化剂。这些催化剂在所有pH条件下在锌空气电池中表现出优异的析氢活性。

其他说明

可溶型

警示用语：

Danger

危险声明

H302,H314,H411

危险分类

Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Skin Corr. 1B

储存分类代码

8A - Combustible corrosive hazardous materials

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
0000419184
0000419183
0000419184
0000419183
MKCX1871

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Fujita, S.-I., et al.
J. Catal., 255, 95-95 (2004)
Cho, C.S. et al.
Tetrahedron Letters, 40, 1499-1499 (1999)
Won-Hee Kim et al.
Organic letters, 8(12), 2543-2545 (2006-06-02)
An efficient oxidant-free oxidation for a wide range of alcohols was achieved by a recyclable ruthenium catalyst. The catalyst was prepared from readily available reagents by a one-pot synthesis through nanoparticle generation and gelation. [structure: see text]
Yao Zhang et al.
European journal of medicinal chemistry, 86, 449-455 (2014-09-10)
Ruthenium-based anticancer complexes have become increasingly popular for study over the last two decades. Although ruthenium complexes are currently being investigated in clinical trials, there are still some difficulties with their delivery and associated side effects. Human serum albumin (HSA)-based
Xingcui Guo et al.
Scientific reports, 5, 16451-16451 (2015-11-19)
Ruthenium (Ru) supported on activated carbon (AC) and carbon nanotubes (CNTs) was carried out in the hydrogenolysis of sorbitol to ethylene glycol (EG) and 1,2-propanediol (1,2-PD) under the promotion of tungsten (WOx) species and different bases. Their catalytic activities and
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