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检测方案
90%
bp
110-112 °C/0.4 mmHg (lit.)
mp
33-38 °C (lit.)
SMILES字符串
BrC1Cc2ccccc2C1=O
InChI
1S/C9H7BrO/c10-8-5-6-3-1-2-4-7(6)9(8)11/h1-4,8H,5H2
InChI key
UXVCSPSWUNMPMT-UHFFFAOYSA-N
一般描述
2-Bromo-1-indanone is a halogenated indanone. It can be obtained via bromination of 1-indanone.
应用
2-Bromo-1-indanone may be used in the preparation of trans-2-benzal-1-indanone epoxide via Darzens-type condensation with benzaldehyde. It may also be employed as substrate to investigate the substrate specificity of recombinant β-keto ester reductase (KER) of Penicillium citrinum.
警示用语：
Danger
危险声明
危险分类
Skin Corr. 1B
WGK
WGK 3
闪点(°F)
closed cup
闪点(°C)
closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
The synthesis of derivatives of 1-indanone and indenone.
House HO, et al.
Journal of the American Chemical Society, 82(6), 1452-1457 (1960)
N Itoh et al.
Applied microbiology and biotechnology, 66(1), 53-62 (2004-09-01)
A novel beta-keto ester reductase (KER) was purified to homogeneity from recombinant Escherichia coli (pTrcKER) cells, which efficiently expressed the ker gene cloned from Penicillium citrinum IFO4631. The enzyme was monomeric and had a molecular mass of 37 kDa. It
Expoxy ketones. VII. The stereochemistry of spiroepoxy ketones. Reactions of 2-benzal-1-indanone oxide.
Cromwell NH and Martin JL.
The Journal of Organic Chemistry, 33(5), 1890-1894 (1968)
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