462063
(R)-(+)-3-Boc-2,2-二甲基噁唑啉-4-甲醛
95%
别名:
(+)-N-Boc-N,O-异亚丙基-D-丝氨醛, (R)-(+)-4-甲酰基-2,2-二甲基-3-噁唑啉羧酸叔丁酯
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关于此项目
经验公式（希尔记法）:
C11H19NO4
化学文摘社编号:
分子量:
229.27
UNSPSC Code:
12352005
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
3651554
产品名称
(R)-(+)-3-Boc-2,2-二甲基噁唑啉-4-甲醛, 95%
InChI
1S/C11H19NO4/c1-10(2,3)16-9(14)12-8(6-13)7-15-11(12,4)5/h6,8H,7H2,1-5H3/t8-/m0/s1
SMILES string
[H]C(=O)[C@H]1COC(C)(C)N1C(=O)OC(C)(C)C
InChI key
PNJXYVJNOCLJLJ-QMMMGPOBSA-N
assay
95%
optical activity
[α]23/D +90°, c = 1 in chloroform
impurities
<6% methyl (R)-(+)-3-(tert-butoxycarbonyl)-2,2-dimethyl-4-oxazolidinecarboxylate (CAS 95715-87-0)
refractive index
n20/D 1.445 (lit.)
bp
67 °C/0.3 mmHg (lit.)
density
1.06 g/mL at 25 °C (lit.)
functional group
aldehyde
ether
Quality Level
Application
用于合成谷氨酸和谷氨酰胺的氟化类似物。
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
215.6 °F - closed cup
flash_point_c
102 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
R Dave et al.
Amino acids, 24(3), 245-261 (2003-04-23)
Gamma-fluorinated analogues of glutamic acid and glutamine are compounds of biological interest. Syntheses of such compounds are extensively reviewed in this article. 4-fluoroglutamic acid was prepared as a mixture of racemic diastereomers by Michael reaction, inverse-Michael reaction or by electrophilic
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